Effect of surfactants on the kinetics of base-catalyzed hydrolysis of methyl, ethyl, isopropyl and n-butyl acetates

被引:0
作者
Choudhury, TR [1 ]
Umlong, IM [1 ]
Bhat, SN [1 ]
机构
[1] NE Hill Univ, Dept Chem, Shillong 793022, Meghalaya, India
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中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The velocity constants of base - catalyzed methyl, ethyl, isopropyl and n-butyl acetates in aqueous and micellar media are determined at different temperatures. The velocity constants in anionic and non-ionic media are higher than those in aqueous media, whereas the energy of activation are lower. The velocity constants for the alkaline hydrolysis of the esters vary in the order : kappa-methyl acetate > kappa-ethyl acetate > kappa-isopropyl acetate < kappa-n-butyl acetate.
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页码:538 / 540
页数:3
相关论文
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