Cathodic reduction of phenacyl azides

被引：21

作者：

Batanero, B ^{[1
]}

Escudero, J ^{[1
]}

Barba, F ^{[1
]}

机构：

[1] Univ Alcala de Henares, Dept Organ Chem, Alcala De Henares 28871, Madrid, Spain

来源：

ORGANIC LETTERS | 1999年 / 1卷 / 10期

关键词：

D O I：

10.1021/ol990200j

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] The electrochemical reduction of phenacyl azides (1a-e) leads to the formation of 2-aroyl-1-4-arylimidazoles (2a-e) (70-80% yield). 1a-e were prepared from phenacyl bromides and sodium azide and were reduced in aprotic DMF-LiClO4 medium at the mercury cathode in a divided cell and under controlled potential.

引用

页码：1521 / 1522

页数：2