Novel and General Method for the Formation of S-Aryl, Se-Aryl, and Te-Aryl Phosphorochalcogenoates

被引：78

作者：

Gao, Yu-Xing ^{[1
,2
]}

Tang, Guo ^{[1
,2
]}

Cao, Yu ^{[1
,2
]}

Zhao, Yu-Fen ^{[1
,2
,3
]}

机构：

[1] Xiamen Univ, Dept Chem, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China

[2] Xiamen Univ, Key Lab Chem Biol Fujian Prov, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China

[3] Tsinghua Univ, Minist Educ, Key Lab Bioorgan Phosphorus Chem & Chem Biol, Beijing 100084, Peoples R China

来源：

SYNTHESIS-STUTTGART | 2009年 / 07期

基金：

国家自然科学基金重大项目;

关键词：

Lewis acids; selenium; phosphorylation; sulfur; tellurium; CARBOHYDRATE DIFLUOROMETHYLENE-PHOSPHONATES; CONVENIENT PREPARATION; HYPERVALENT IODINE; CHEMICAL-SYNTHESIS; FACILE; PHOSPHOROTHIOATE; EPOXIDES; RIBOSE; ESTERS; ACID;

D O I：

10.1055/s-0028-1088012

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new and general method for the synthesis of S-, Se-, and Te-aryl phosphorochalcogenoates (chalcogenophosphates) has been developed. S-P, Se-P, and Te-P bonds were formed by the coupling of readily available dialkyl phosphites with diaryl dichalcogenides at 30 degrees C in dimethyl sulfoxide in the presence of catalytic amounts of copper iodide and diethylamine. The reaction proceeded smoothly without exclusion of moisture or air.

引用

页码：1081 / 1086

页数：6

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