A high-nuclearity isopolyoxotungstate based manganese cluster: one-pot synthesis and step-by-step assembly

被引：24

作者：

Zhang, Chao ^{[1
]}

Zhang, Mengrui ^{[1
]}

Shi, Hongyu ^{[2
]}

Zeng, Qingdao ^{[2
]}

Zhang, Dongdi ^{[1
]}

Zhao, Yaqing ^{[1
]}

Wang, Yuan ^{[1
]}

Ma, Pengtao ^{[1
]}

Wang, Jingping ^{[1
]}

Niu, Jingyang ^{[1
]}

机构：

[1] Henan Univ, Coll Chem & Chem Engn, Henan Key Lab Polyoxometalate Chem, Kaifeng 475004, Henan, Peoples R China

[2] Natl Ctr Nanosci & Technol, CAS Ctr Excellence Nanosci, CAS Key Lab Standardizat & Measurement Nanotechno, 11 Beiyitiao, Beijing 100190, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2018年 / 54卷 / 43期

基金：

中国国家自然科学基金;

关键词：

SINGLE-MOLECULE MAGNETS; MASS-SPECTROMETRY; POLYOXOMETALATE; TRANSFORMATION; CORE; REACTIVITY; NETWORKS; COMPLEX; BARRIER; SURFACE;

D O I：

10.1039/c8cc01622d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A manganese(iii,iv)-tungsten(vi) supercluster based on 72 manganese ions (48 Mn-IV and 24 Mn-III) and 48 tungsten(vi) centers [{(Mn24Mn12O28)-Mn-IV-O-III(H2O)(23)}(2)(W24O120)(2)](40-) has been prepared from the carboxylic Mn-12 cluster. Its structure comprises two unprecedented cage-like Mn36W24 cores linked via two Mn-O-W bonds, leading to a Mn72W48 assembly. The inorganic synthetic mechanism was investigated through different synthesis methods and comprehensive ESI-MS tests.

引用

页码：5458 / 5461

页数：4

共 49 条

[1] The manganese(III)-containing tungstophosphate [Mn3III(H2O)5(A-α-PW9O34)]9- [J].

Al-Oweini, Rami ;

Bassil, Bassem S. ;

Palden, Thupten ;

Keita, Bineta ;

Lan, Yanhua ;

Powell, Annie K. ;

Kortz, Ulrich .

POLYHEDRON, 2013, 52 :461-466

[2] X-RAY PHOTOELECTRON SPECTROSCOPIC STUDIES ON ZNS-MNF2 PHOSPHORS [J].

AOKI, A .

JAPANESE JOURNAL OF APPLIED PHYSICS, 1976, 15 (02) :305-311

[3] The Drosophila of single-molecule magnetism: [Mn12O12(O2CR)16(H2O)4] [J].

Bagai, Rashmi ;

Christou, George .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (04) :1011-1026

[4] Revealing the structure of the Mn-cluster of photosystem 11 by X-ray crystallography [J].

Barber, James ;

Murray, James W. .

COORDINATION CHEMISTRY REVIEWS, 2008, 252 (3-4) :233-243

[5] A Planar {Mn19(OH)12}26+ Unit Incorporated in a 60-Tungsto-6-Silicate Polyanion [J].

Bassil, Bassem S. ;

Ibrahim, Masooma ;

Al-Oweini, Rami ;

Asano, Marie ;

Wang, Zhenxing ;

van Tol, Johan ;

Dalal, Naresh S. ;

Choi, Kwang-Yong ;

Rosa Ngo Biboum ;

Keita, Bineta ;

Nadjo, Louis ;

Kortz, Ulrich .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (26) :5961-5964

[6] X-RAY PHOTOELECTRON-SPECTROSCOPY STUDY OF THE CATION VALENCIES IN NICKEL MANGANITE [J].

BRABERS, VAM ;

VANSETTEN, FM ;

KNAPEN, PSA .

JOURNAL OF SOLID STATE CHEMISTRY, 1983, 49 (01) :93-98

[7] Self-assembly and structural transformations of high-nuclearity palladium-rich polyoxometalates [J].

Cameron, Jamie M. ;

Gao, Jing ;

Long, De-Liang ;

Cronin, Leroy .

INORGANIC CHEMISTRY FRONTIERS, 2014, 1 (02) :178-185

[8] Formation, self-assembly and transformation of a transient selenotungstate building block into clusters, chains and macrocycles [J].

Cameron, Jamie M. ;

Gao, Jing ;

Vila-Nadal, Laia ;

Long, De-Liang ;

Cronin, Leroy .

CHEMICAL COMMUNICATIONS, 2014, 50 (17) :2155-2157

[9] Hierarchical Assembly of a {Mn15IIMn4III} Brucite Disc: Step-by-Step Formation and Ferrimagnetism [J].

Deng, Yong-Kai ;

Su, Hai-Feng ;

Xu, Jia-Heng ;

Wang, Wen-Guang ;

Kurmoo, Mohamedally ;

Lin, Shui-Chao ;

Tan, Yuan-Zhi ;

Jia, Jiong ;

Sun, Di ;

Zheng, Lan-Sun .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (04) :1328-1334

[10] Narrowing the Zero-Field Tunneling Resonance by Decreasing the Crystal Symmetry of Mn12 Acetate [J].

Espin, Jordi ;

Zarzuela, Ricardo ;

Statuto, Nahuel ;

Juanhuix, Jordi ;

Maspoch, Daniel ;

Imaz, Inhar ;

Chudnovsky, Eugene ;

Tejada, Javier .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (29) :9065-9068

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