On the Reaction of 2-Benzylamino-1,4-naphthoquinones with Nitrosylsulfuric Acid

被引：1

作者：

Gornostaev, L. M. ^{[1
]}

Nuretdinova, E. V. ^{[1
]}

Lavrikova, T. I. ^{[1
]}

Khalyavina, Yu. G. ^{[1
]}

Fominykh, O. I. ^{[1
]}

Gatilov, Yu. V. ^{[2
,3
]}

机构：

[1] Astafev Krasnoyarsk State Pedag Univ, Ul A Lebedevoy 89, Krasnoyarsk 660049, Russia

[2] RAS, SB, Vorozhtsov Novosibirsk Inst Organ Chem, Pr Akad Lavrentieva 9, Novosibirsk 630090, Russia

[3] Novosibirsk State Univ, Ul Pirogova 2, Novosibirsk 630090, Russia

来源：

RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2019年 / 55卷 / 05期

关键词：

2-benzylamino-1; 4-naphthoquinone; hydroxyimidazole; naphtho-1; 2-oxazole; oximes; 2; 3-diazido-1; nitrosylsulfuric acid; 2-ALKYLAMINO-1,4-NAPHTHOQUINONES; DERIVATIVES;

D O I：

10.1134/S1070428019050051

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of 2-benzylamino-1,4-naphthoquinone with nitrosylsulfuric acid in acetic acid results in preferential formation of 2,1- and 2,3-heterocyclization products: (E)-4-(hydroxyimino)-2-phenylnaphtho [2,1-d]oxazol-5(4H)-one and 2-phenyl-1-hydroxy-1H-naphtho[2,3-d]imidazole-4,9-dione. In addition, 2-phenylnaphtho[2,1-d]oxazol-4,5-dione and N-(3-nitro-1,4-dioxo-1,4-dihydronaphthalen-2-yl)benzamide are also formed. The reaction of 2-benzylamino-3-chloro-1,4-naphthoquinone with nitrosylsulfuric acid in acetic acid gives 3-diazonapthalene-1,2,4(3H)-trione and benzaldehyde.

引用

页码：608 / 614

页数：7

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