Three multinuclear metal-organic coordination compounds based on 8-hydroxyquinoline derivative: Syntheses, structures and fluorescence properties

被引：9
|
作者：
Shi, Jiangjiao [1 ]
Gong, Chunhua [1 ]
Zeng, Xianghua [1 ]
Zhang, Junyong [1 ]
Zhu, Chengfeng [1 ]
Xie, Jingli [1 ,2 ]
机构：
[1] Jiaxing Univ, Coll Biol Chem Sci & Engn, Jiaxing 314001, Peoples R China
[2] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China
来源：
POLYHEDRON | 2015年 / 102卷
基金：
中国国家自然科学基金;
关键词：
8-Hydroxy quinoline derivatives; Metal-organic coordination compounds; Crystal structure; Solid state fluorescence; Multinuclear cluster; DINUCLEAR COPPER(II) COMPLEXES; CRYSTAL-STRUCTURES; LUMINESCENT PROPERTIES; POLYMERS; FRAMEWORK; SERIES; ZN(II); LIGAND; CAGE;
D O I：
10.1016/j.poly.2015.10.002
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
By taking advantage of the synthetic 8-hydroxyquinoline derivative, (E)-242-(4-chlorophenyl)vinyl]-8-hydroxyquinoline (HL), three new metal-organic coordination compounds [Zn3L6] (1), [Cd3L6] (2) and [Cu2L4] (3) have been obtained by solvothermal or solution processing methods and structurally characterized. Single crystal X-ray diffraction analysis revealed that complexes 1 and 2 have similar trinuclear structures. Different from complexes 1 and 2 (trinuclear structure), complex 3 displays dinuclear structure. The effects of central metals and reaction solvents on the structures of complexes 1-3 have been discussed. Furthermore, thermogravimetric analysis and solid state fluorescence of ligand HL, 1-3 were investigated. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码：562 / 568
页数：7
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