Copper-Catalyzed Oxidative C-H Bond Functionalization of N-Allylbenzamide for Regioselective C-N and C-O Bond Formation

被引：6

作者：

Ranjith, Jala ^{[1
]}

Krishna, Palakodety Radha ^{[1
]}

机构：

[1] Indian Inst Chem Technol, CSIR, Organ Synth & Proc Chem Div, Hyderabad 500007, Telangana, India

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2019年 / 14卷 / 09期

关键词：

copper; imides; oxidative coupling; oxo-amination; regioselectivity; IMIDES; AMIDATION; ALDEHYDES; CONVERSION; ARYLATION; OLEFINS; AMINES;

D O I：

10.1002/asia.201900192

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Copper-catalyzed oxidative couplings of N-allylbenzamides for C-N and C-O bond formations have been developed through C-H bond functionalization. To demonstrate the utility of this approach, it was applied to the synthesis of -aminoimides and imides. To the best of our knowledge, these are the first examples in which different classes of N-containing compounds have been directly prepared from the readily available N-allylbenzamides using an inexpensive catalyst/oxidant/base (CuSO4/TBHP/Cs2CO3) system.

引用

页码：1448 / 1451

页数：4

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