Transition-metal-free oxidative amidation of benzyl alcohols with amines catalyzed by NaI: a new method for the synthesis of benzamides

被引：30
作者：
Karimi, Meghdad [1 ]
Saberi, Dariush [2 ]
Azizi, Kobra [1 ]
Arefi, Marzban [1 ]
Heydari, Akbar [1 ]
机构：
[1] Tarbiat Modares Univ, Dept Chem, Tehran, Iran
[2] Persian Gulf Univ, Coll Agr & Nat Resources, Dept Fisheries & Aquaculture, Bushehr 75169, Iran
来源：
TETRAHEDRON LETTERS | 2014年 / 55卷 / 39期
关键词：
Benzyl alcohol; Amine; Oxidative amidation; Sodium iodide; AMIDE BOND FORMATION; CARBOXYLIC-ACIDS; TERTIARY-AMINES; MILD AMIDATION; ALDEHYDES; HYDROCHLORIDE; TRANSAMIDATION; AMINATION; SECONDARY; PEPTIDES;
D O I：
10.1016/j.tetlet.2014.07.085
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A simple, inexpensive, and efficient method for the synthesis of benzamides via the reaction of benzyl alcohols and amine hydrochloride salts in the presence of NaI as a green catalyst is described. Various derivatives of benzamide were synthesized in moderate to good yields using this method. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码：5351 / 5353
页数：3
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