A 3D Luminescent Metal-organic Framework Constructed from Cu4I4 Cubane Clusters and Triangular Imidazole Ligand

被引：17

作者：

Liu, Shan-Shan ^{[1
]}

Yuan, Shuai ^{[1
]}

Hu, Tuo-Ping ^{[2
]}

Sun, Di ^{[1
]}

机构：

[1] Shandong Univ, Sch Chem & Chem Engn, Key Lab Colloid & Interface Chem, Educ Minist, Jinan 250100, Peoples R China

[2] North Univ China, Dept Chem, Taiyuan 030051, Shanxi, Peoples R China

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2014年 / 640卷 / 10期

基金：

中国博士后科学基金; 中国国家自然科学基金;

关键词：

COORDINATION POLYMERS; COPPER(I) HALIDES; HYDROGEN-BONDS; THERMOCHROMISM; TEMPERATURE; COMPLEXES; VOLUMES;

D O I：

10.1002/zaac.201400071

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The solvothermal reaction between cuprous iodide and the rigid triangular imidazole ligand in mixed N,N'-dimethylacetamide (DMA)-acetonitrile solvent leads to the isolation of the 3D metal-organic framework [(Cu4I4)(3)(TIPA)(4)]center dot 7DMA (1) [TIPA = tri(4-imidazolylphenyl) amine], which was characterized by elemental analysis, IR spectroscopy, powder X-ray diffraction, and single-crystal X-ray diffraction. Topologically, the structure of 1 is an unprecedented 3,3,4,4-connected net with a point symbol of {4.8.10}(2){4.8(2)}(2){4(2).8(2).10(2)}(2){8(4).12(2)}. Compound 1 exhibits orange-red photoluminescence with an emission maximum at 622 nm at room temperature.

引用

页码：2030 / 2034

页数：5

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