Performance of Electrolyte Supported Solid Oxide Fuel Cells with STN Anodes

被引:5
作者
Veltze, S. [1 ]
Sudireddy, B. R. [1 ]
Jorgensen, P. S. [1 ]
Zhang, W. [1 ]
Kuhn, L. T. [1 ]
Holtappels, P. [1 ]
Ramos, T. [1 ]
机构
[1] Tech Univ Denmark, Dept Energy Convers & Storage, DK-4000 Roskilde, Denmark
来源
SOLID OXIDE FUEL CELLS 13 (SOFC-XIII) | 2013年 / 57卷 / 01期
关键词
NB-DOPED SRTIO3; SOFC ANODES; TEMPERATURE; REDUCTION; OXIDATION; BEHAVIOR;
D O I
10.1149/05701.0743ecst
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
In order to replace the state of the art Ni-cermet as SOFC anode, electrolyte supported cells comprising CGO/Ni infiltrated Nb-doped SrTiO3 anodes, and LSM/YSZ cathodes have been developed and tested as single 5 x 5 cm(2) cells. The initial performance reached 0.4 W/cm(2) at 850 degrees C. Further tests under high fuel utilization and redox cycling have been performed to identify the performance limiting parameters in this new type of full ceramic SOFCs. Measured performances and stability have been further tentatively linked to modifications of the nano-sized infiltrates within the anode.
引用
收藏
页码:743 / 752
页数:10
相关论文
共 16 条
[1]   Advanced anodes for high-temperature fuel cells [J].
Atkinson, A ;
Barnett, S ;
Gorte, RJ ;
Irvine, JTS ;
Mcevoy, AJ ;
Mogensen, M ;
Singhal, SC ;
Vohs, J .
NATURE MATERIALS, 2004, 3 (01) :17-27
[2]  
Barsoukov E, 2005, IMPEDANCE SPECTROSCOPY: THEORY, EXPERIMENT, AND APPLICATIONS, 2ND EDITION, P1, DOI 10.1002/0471716243
[3]   Electrochemical characterization and redox behavior of Nb-doped SrTiO3 [J].
Blennow, Peter ;
Hansen, Kent K. ;
Wallenberg, L. Reine ;
Mogensen, Mogens .
SOLID STATE IONICS, 2009, 180 (01) :63-+
[4]   Performance and durability of solid oxide electrolysis cells [J].
Hauch, A. ;
Jensen, S. H. ;
Ramousse, S. ;
Mogensen, M. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2006, 153 (09) :A1741-A1747
[5]   Synthesis and Electrical Characterisation of the Perovskite Niobate-Titanates, Sr1-x/2Ti1-xNbxO3-δ [J].
Irvine, J. T. S. ;
Slater, P. R. ;
Wright, P. A. .
IONICS, 1996, 2 (3-4) :213-216
[6]   A review of anode materials development in solid oxide fuel cells [J].
Jiang, SP ;
Chan, SH .
JOURNAL OF MATERIALS SCIENCE, 2004, 39 (14) :4405-4439
[7]   Solid oxide fuel cells with Ni-infiltrated perovskite anode [J].
Karczewski, J. ;
Bochentyn, B. ;
Molin, S. ;
Gazda, M. ;
Jasinski, P. ;
Kusz, B. .
SOLID STATE IONICS, 2012, 221 :11-14
[8]   The mechanism behind redox instability of anodes in high-temperature SOFCs [J].
Klemenso, T ;
Chung, C ;
Larsen, PH ;
Mogensen, M .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2005, 152 (11) :A2186-A2192
[9]   Nonstoichiometric Y-substituted SrTiO3 materials as anodes for solid oxide fuel cells [J].
Ma, Qianli ;
Tietz, Frank ;
Stoever, Detlev .
SOLID STATE IONICS, 2011, 192 (01) :535-539
[10]   Reduction and re-oxidation of anodes for solid oxide fuel cells [J].
Malzbender, J ;
Wessel, E ;
Steinbrech, RW .
SOLID STATE IONICS, 2005, 176 (29-30) :2201-2203