Solvent-free condensation of pyrrole and pentafluorobenzaldehyde:: A novel synthetic pathway to corrole and oligopyrromethenes

被引：287

作者：

Gross, Z ^{[1
]}

Galili, N

Simkhovich, L

Saltsman, I

Botoshansky, M

Bläser, D

Boese, R

Goldberg, I

机构：

[1] Technion Israel Inst Technol, Dept Chem, IL-32000 Haifa, Israel

[2] Univ Essen Gesamthsch, Inst Inorgan Chem, D-45117 Essen, Germany

[3] Tel Aviv Univ, Sch Chem, IL-69978 Tel Aviv, Israel

来源：

ORGANIC LETTERS | 1999年 / 1卷 / 04期

关键词：

D O I：

10.1021/ol990739h

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] The solvent-free condensation of pyrrole and pentafluorobenzaldehyde (and to a lesser extent other electron poor aldehydes as well) leads to a variety of products, of which three have been isolated and fully characterized. The two main products (11% each) are an open-chain pentapyrrole and corrole, a tetrapyrrolic macrocycle.

引用

页码：599 / 602

页数：4

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