Synthesis of new bulky isocyanide ligands and their use for Rh-catalyzed hydrosilylation

被引：16

作者：

Ito, Hajime ^{[1
]}

Kato, Takayuki ^{[1
]}

Sawamura, Masaya ^{[1
]}

机构：

[1] Hokkaido Univ, Fac Sci, Dept Chem, Sapporo, Hokkaido 060810, Japan

来源：

CHEMISTRY LETTERS | 2006年 / 35卷 / 09期

关键词：

D O I：

10.1246/cl.2006.1038

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bulky isocyanide ligands having meta-terphenyl backbone were developed. Their usefulness as a supporting ligand in catalysis was illustrated by the application to the rhodium-catalyzed hydrosilylation of cyclohexanone. The combined effect of the high ligand affinity to the rhodium atom and the ligand bulkiness to facilitate the formation of a catalytically active, monoligated isocyanide-rhodium species was proposed.

引用

页码：1038 / 1039

页数：2

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