Ligand isomerism-controlled structural diversity of three new Cd(II) coordination polymers constructed by mixed dipyridyl-containing and benzenedicarboxylate ligands: syntheses, crystal structures, and photoluminescent properties

被引：1
作者：
Zhang, Xiuling [1 ]
Wang, Yujing [1 ]
机构：
[1] Peoples Hosp Yucheng, Yucheng 251200, Shandong, Peoples R China
来源：
INORGANIC AND NANO-METAL CHEMISTRY | 2017年 / 47卷 / 07期
关键词：
Cadmium (II); crystal structure; luminescent property; METAL-ORGANIC FRAMEWORKS; TOPOLOGIES; ZN(II);
D O I：
10.1080/15533174.2016.1228669
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three new cadmium coordination polymers, [Cd(1,2-BDC)(L-1)(0.5)(H2O)(2)](n)(1), [Cd(1,2-BDC)(L-2) (H2O)](n) (2) and {[Cd(1,3-BDC) (L-2)(0.5) (H2O)]center dot H2O}(n) (3), have been successfully synthesized by the assembly of Cd2+ ion, isomeric dipyridyl [L-1 = 1,4-bis(4-pyridylmethyl) piperazine and L-2 = 1,4-bis(3-pyridylmethyl) piperazine], and isomeric dicarboxylate ligands [1,2-H2BDC = 1.2-benzene dicarboxylic acid and 1,3-H2BDC = 1.3-benzene-dicarboxylic acid], respectively. Complexes 1 and 2 all show 2D layer structures. The complex 3 displays 1D ladder-like structure. Furthermore, the luminescent properties of complexes 1-3 are investigated in solid state at room temperature.
引用
收藏
页码：978 / 983
页数：6
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