Synthesis and characterization of cellulose triacetate and poly(ethylene imine) membranes containing a polyether macrobicyclic: Their application to the separation of copper(II) and silver(I) ions

被引:34
作者
Arous, O [1 ]
Amara, M [1 ]
Kerdjoudj, H [1 ]
机构
[1] Univ Sci & Technol Houari Boumediene, Fac Chim, Lab Hydromet & Chim Inorgan Mol, Algiers, Algeria
关键词
diffusion; membranes; synthesis;
D O I
10.1002/app.20510
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A cellulose triacetate (CTA)-poly(ethylene imine) (PEI) membrane containing a polyether macrobicyclic (crytand) as a carrier and 2-nitrophenyloctyl ether (NPOE) as a plasticizer was prepared. The CTA-PEI-c-ryptand-NPOE membrane was characterized with chemical techniques as well as Fourier transform infrared, X-ray diffraction, differential scanning calorimetry, and scanning electron microscopy. The permeation of silver and copper ions through the CTA-PEI-cryptand-NPOE membrane was comparable to that through a supported liquid membrane. (C) 2004 Wiley Periodicals, Inc.
引用
收藏
页码:1401 / 1410
页数:10
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