Enhancement of mechanical properties of epoxy/halloysite nanotube (HNT) nanocomposites

被引:52
作者
Ravichandran, G. [1 ]
Rathnakar, G. [2 ]
Santhosh, N. [1 ]
Chennakeshava, R. [1 ]
Hashmi, Mosharib Ahmad [1 ]
机构
[1] CHRIST Deemed Be Univ, Dept Mech & Automobile Engn, Mysore Rd, Bangalore 560074, Karnataka, India
[2] ATME Coll Engn, Dept Mech Engn, Mysore 570028, Karnataka, India
来源
SN APPLIED SCIENCES | 2019年 / 1卷 / 04期
关键词
Halloysite nanotube (HNT); Epoxy; Ultrasonication; Solution casting; Mechanical properties; EPOXY NANOCOMPOSITES; HALLOYSITE CLAY; FUNCTIONALIZATION; BEHAVIOR;
D O I
10.1007/s42452-019-0323-9
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
The particulate filled epoxy composites show lower mechanical properties than neat composites due to lack strength of uniform dispersion of particles leading to poor in interfacial strength between matrix and fillers. In this study, ultrasonification dispersion technique is employed to achieve a homogenous dispersion of halloysite nanotubes (HNTs) in epoxy resin. The nanocomposites are fabricated by solution casting method and specimens are prepared as per ASTM standards. The various test has been conducted as per ASTM procedure to evaluate the mechanical properties viz. density, hardness, tensile, flexural, ILSS and impact strength of the nanocomposites consisting of different weight (wt)% of HNTs varying in the range of 0-4 with the interval of 1. As per the experimental investigation, the selected dispersion techniques enhances the mechanical properties of the nanocomposite by the loading of HNT. Further, the study revealed that the 3 wt% of HNT with ultrasonic homogenized nanocomposite shows superior mechanical strength as compared to other nanocomposites. Hence it is evident that the properties of the nanocomposite depends on the quantity of filler present and dispersion condition. The dispersion condition and fractured surfaces are analyzed through the SEM micrographs.
引用
收藏
页数:8
相关论文
共 19 条
[1]   Synthesis and characterization of epoxy based nanocomposites [J].
Basara, G ;
Yilmazer, U ;
Bayram, G .
JOURNAL OF APPLIED POLYMER SCIENCE, 2005, 98 (03) :1081-1086
[2]   The influence of silicate-based nano-filler on the fracture toughness of epoxy resin [J].
Brunner, A. J. ;
Necola, A. ;
Rees, M. ;
Gasser, Ph. ;
Kornmann, X. ;
Thomann, R. ;
Barbezat, M. .
ENGINEERING FRACTURE MECHANICS, 2006, 73 (16) :2336-2345
[3]   Toughening epoxies with halloysite nanotubes [J].
Deng, Shiqiang ;
Zhang, Jianing ;
Ye, Lin ;
Wu, Jingshen .
POLYMER, 2008, 49 (23) :5119-5127
[4]   Fracture behaviours of epoxy nanocomposites with nano-silica at low and elevated temperatures [J].
Deng, Shiqiang ;
Ye, Lin ;
Friedrich, Klaus .
JOURNAL OF MATERIALS SCIENCE, 2007, 42 (08) :2766-2774
[5]   Halloysite-epoxy nanocomposites with improved particle dispersion through ball mill homogenisation and chemical treatments [J].
Deng, Shiqiang ;
Zhang, Jianing ;
Ye, Lin .
COMPOSITES SCIENCE AND TECHNOLOGY, 2009, 69 (14) :2497-2505
[6]   Thermal stability and flame retardant effects of halloysite nanotubes on poly(propylene) [J].
Du, Mingliang ;
Guo, Baochun ;
Jia, Demin .
EUROPEAN POLYMER JOURNAL, 2006, 42 (06) :1362-1369
[7]   Reinforcing and Flame-Retardant Effects of Halloysite Nanotubes on LLDPE [J].
Jia, Zhixin ;
Luo, Yuanfang ;
Guo, Baochun ;
Yang, Bingtao ;
Du, Mingliang ;
Jia, Demin .
POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING, 2009, 48 (06) :607-613
[8]   Halloysite clay minerals - A review [J].
Joussein, E ;
Petit, S ;
Churchman, J ;
Theng, B ;
Righi, D ;
Delvaux, B .
CLAY MINERALS, 2005, 40 (04) :383-426
[9]   Behavior of halloysite clay under formamide treatment [J].
Joussein, Emmanuel ;
Petit, Sabine ;
Delvaux, Bruno .
APPLIED CLAY SCIENCE, 2007, 35 (1-2) :17-24
[10]   Influence of nanofillers on the deformation process in layered silicate/polyamide-12 nanocomposites [J].
Kim, GM ;
Lee, DH ;
Hoffmann, B ;
Kressler, J ;
Stöppelmann, G .
POLYMER, 2001, 42 (03) :1095-1100