Asymmetric lithium(I) and copper(II) alkoxy-N-heterocyclic carbene complexes;: crystallographic characterisation and Lewis acid catalysis

被引：208

作者：

Arnold, PL ^{[1
]}

Rodden, M ^{[1
]}

Davis, KM ^{[1
]}

Scarisbrick, AC ^{[1
]}

Blake, AJ ^{[1
]}

Wilson, C ^{[1
]}

机构：

[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 14期

关键词：

D O I：

10.1039/b404614e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A one-pot synthesis of a wide range of bidentate, alkoxide-N-heterocyclic carbene ligands provides new lithium alkoxycarbenes and a range of covalently bound organometallic Cu(II) carbene complexes, which are catalytically active, in some cases enantioselectively, for conjugate addition reactions.

引用

页码：1612 / 1613

页数：2

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