The surprise synthesis of α-GlcNAc 1-C-sulfonates

被引：9

作者：

Knapp, S ^{[1
]}

Darout, E ^{[1
]}

机构：

[1] Rutgers State Univ, Dept Chem & Chem Biol, Piscataway, NJ 08854 USA

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 34期

关键词：

D O I：

10.1016/S0040-4039(02)01218-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Oxidation of GlcNAc thiazoline in the presence of an alcohol affords no glycosidation products, but rather the alkyl alpha-GlcNAc 1-C-sulfonate. E2 cleavage of the sulfonate ester and then O-deacetylation gives the alpha-GlcNAc 1-C-sulfonic acid, a new type of carbohydrate derivative. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：6075 / 6078

页数：4

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