Direct observation of adsorbed H2-framework interactions in the Prussian Blue analogue MnII3[CoIII(CN)6]2:: The relative importance of accessible coordination sites and van der Waals interactions

被引：60

作者：

Chapman, Karena W. ^{[1
]}

Chupas, Peter J.

Maxey, Evan R.

Richardson, James W.

机构：

[1] Argonne Natl Lab, Adv Photon Source, Xray Sci Div, 9700 S Cass Ave, Argonne, IL 60439 USA

[2] Argonne Natl Lab, Intense Pulsed Neutron Source, Argonne, IL 60439 USA

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 38期

关键词：

D O I：

10.1039/b607250j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Selective recovery of the guest-framework interactions for H-2 adsorbed in a nanoporous Prussian Blue analogue, through differential X-ray and neutron pair distribution function analysis at ca. 77 K, suggests that the H-2 molecule is disordered about a single position at the centre of the pore, (1/4, 1/4, 1/4), without binding at accessible Mn-II sites.

引用

页码：4013 / 4015

页数：3

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