Synthesis, Structure and Properties of Poly(arylene imino)s

被引：5

作者：

Zhang Lin ^{[1
]}

Chang Guanjun ^{[1
,2
]}

机构：

[1] China Acad Engn Phys, Res Ctr Laser Fus, Mianyang 621900, Sichuan, Peoples R China

[2] Qingdao Univ Sci & Technol, Key Lab Rubber Plast, Educ Minist, Qingdao 266042, Shandong, Peoples R China

来源：

CHINESE JOURNAL OF CHEMISTRY | 2009年 / 27卷 / 02期

关键词：

poly(arylene imino); diiodobenzene; romatic diimino; polymerization; PALLADIUM-CATALYZED AMINATION; ARYL BROMIDES; AROMATIC DIAMINES; BOND FORMATION; HALIDES; POLYMERS; SCOPE; DYES;

D O I：

10.1002/cjoc.200990071

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of poly(arylene imino)s (PAI) with high molecular weights and small polydispersity indices have been synthesized by the condensation polymerization of different diiodobenzenes with aromatic primary diiminos via two different methods. Their structures were characterized by means of FT-IR, H-1 NMR spectroscopy and elemental analysis. DSC and TG measurements show that the polymers possess high glass transition temperatures (T-g>150 degrees C) and good thermal stability with high decomposition temperatures (T-D>400 degrees C). These novel polymers also exhibit good solubility in organic solvents.

引用

页码：428 / 432

页数：5

共 29 条

[1]

ANTISAR RH, 2008, MACROMOLECULES, V41, P1912

[2] Titanocene-based method for indole synthesis [J].

Aoki, K ;

Peat, AJ ;

Buchwald, SL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (13) :3068-3073

[3]

AYMAN SA, 2004, MACROMOLECULES, V37, P8269

[4]

Becker S, 2000, CHEM-EUR J, V6, P3984, DOI 10.1002/1521-3765(20001103)6:21<3984::AID-CHEM3984>3.0.CO

[5]

2-F

[6] Synthesis and properties of novel poly(amine ether)s [J].

Chang Guan-Jun ;

Xu Zhe ;

Lin Run-Xiong ;

Luo Xuan .

CHINESE JOURNAL OF CHEMISTRY, 2007, 25 (08) :1207-1211

[7] Synthesis of novel high-performance polymers via Pd-catalyzed amination of dibromoarenes with primary aromatic diamines [J].

Chang, Guanjun ;

Luo, Xuan ;

Zhang, Lin ;

Lin, Runxiong .

MACROMOLECULES, 2007, 40 (24) :8625-8630

[8] Segmented polyimides with poly(ethylene oxide) blocks exhibiting liquid crystallinity [J].

Costa, G. ;

Eastmond, G. C. ;

Fairclough, J. P. A. ;

Paprotny, J. ;

Ryan, A. J. ;

Stagnaro, P. .

MACROMOLECULES, 2008, 41 (03) :1034-1040

[9] SYNTHESIS AND CHARACTERIZATION OF POLYANILINE DERIVATIVES - POLY(2-ALKOXYANILINES) AND POLY(2,5-DIALKOXYANILINES) [J].

DAPRANO, G ;

LECLERC, M ;

ZOTTI, G ;

SCHIAVON, G .

CHEMISTRY OF MATERIALS, 1995, 7 (01) :33-42

[10]

DENG JG, 2002, POLYM B, V3, P33

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