Preparation and characterization of electroactive anion-exchange acrylic polymer-gold composites

被引：12

作者：

Jeong, Han Mo ^{[1
]}

Jo, Ah Young

Choi, Mi Yeon

Han, Man Jae

Jho, Jae Young

机构：

[1] Univ Ulsan, Dept Chem, Ulsan 680749, South Korea

[2] Seoul Natl Univ, Sch Chem & Biol Engn, Seoul, South Korea

来源：

JOURNAL OF MACROMOLECULAR SCIENCE PART B-PHYSICS | 2006年 / 45卷 / 05期

关键词：

ionic polymer-metal composite (IPMC); anion-exchange membrane; fluoroacrylic copolymer; actuation; ion content; counter anion;

D O I：

10.1080/00222340600870366

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The characteristics and performance of an ionic polymer-metal composite (IPMC), prepared with an anion-exchange acrylic copolymer, was examined. The acrylic copolymer was synthesized by the radical copolymerization of fluoroalkyl methacrylate and 2-(dimethyl amino)ethyl methacrylate(AMA). Effects of the AMA repeating unit's content in the copolymer and effects of the anion type present on the actuation of the IPMC were observed. The optimal content of 19.4% AMA in the IPMC copolymer yielded the best actuation. The actuation also improved according to the type of anion present in the composite, in the following order: Br- < Cl- < F- < ClO4-.

引用

页码：789 / 799

页数：11

共 15 条

[1]

Abe Y, 1998, POLYM ADVAN TECHNOL, V9, P520, DOI 10.1002/(SICI)1099-1581(199808)9:8<520::AID-PAT791>3.0.CO

[2]

2-G

[3] BENDING OF POLYELECTROLYTE MEMBRANE-PLATINUM COMPOSITES BY ELECTRIC STIMULI .1. RESPONSE CHARACTERISTICS TO VARIOUS WAVE-FORMS [J].