Reversible plasticity shape memory effect in epoxy/CNT nanocomposites - A theoretical study

被引:27
作者
Abishera, R. [1 ]
Velmurugan, R. [1 ]
Gopal, K. V. Nagendra [1 ]
机构
[1] Indian Inst Technol Madras, Dept Aerosp Engn, Chennai 600036, Tamil Nadu, India
关键词
Carbon nanotubes; Smart materials; Plastic deformation; Thermomechanical properties; Modeling; WALLED-CARBON-NANOTUBES; CONSTITUTIVE MODEL; THERMOMECHANICAL BEHAVIOR; LARGE DEFORMATIONS; GLASS-TRANSITION; FIBER WAVINESS; POLYMERS; COMPOSITES; RELAXATION; POLYURETHANE;
D O I
10.1016/j.compscitech.2017.01.020
中图分类号
TB33 [复合材料];
学科分类号
摘要
A theoretical investigation on the reversible plasticity shape memory (RPSM) properties of Multi -Walled Carbon Nanotubes (MWCNT) reinforced epoxy nanocomposites is presented. A typical RPSM cyde involves loading and stress relaxation below the glass transition temperature and unconstrained strain recovery above glass transition temperature. This paper attempts to study the underlying mechanisms by employing a thermo-visco-elastic model incorporating structural and stress relaxation mechanisms. The effective properties of the nanocomposites were determined from basic micro -mechanics models and standard thermo-mechanical experiments. The variations in model parameters between neat and filled epoxy were studied and the influence of MWCNT on the material behavior are discussed. The simulations agreed quite well with the experimental results for both neat and filled epoxy. The model was further able to capture the thermo-mechanical behavior under different programming conditions like strain rate, strain level and relaxation time. (C)2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码:145 / 153
页数:9
相关论文
共 47 条
[31]  
SCHERER GW, 1984, J AM CERAM SOC, V67, P504, DOI 10.1111/j.1151-2916.1984.tb19643.x
[32]  
SIMO JC, 1985, COMPUT METHOD APPL M, V51, P177, DOI 10.1016/0045-7825(85)90033-7
[33]   Quantitative analysis of errors in TMDSC in the glass transition region [J].
Simon, SL ;
McKenna, GB .
THERMOCHIMICA ACTA, 2000, 348 (1-2) :77-89
[34]   A hybrid method for computing the effective properties of composites containing arbitrarily shaped inclusions [J].
Srinivasulu, G. ;
Velmurugan, R. ;
Jayasankar, S. .
COMPUTERS & STRUCTURES, 2015, 150 :63-70
[35]   Thermally actuated shape-memory polymers: Experiments, theory, and numerical simulations [J].
Srivastava, Vikas ;
Chester, Shawn A. ;
Anand, Lallit .
JOURNAL OF THE MECHANICS AND PHYSICS OF SOLIDS, 2010, 58 (08) :1100-1124
[36]   Nanocomposites in context [J].
Thostenson, ET ;
Li, CY ;
Chou, TW .
COMPOSITES SCIENCE AND TECHNOLOGY, 2005, 65 (3-4) :491-516
[37]   Advances in the science and technology of carbon nanotubes and their composites: a review [J].
Thostenson, ET ;
Ren, ZF ;
Chou, TW .
COMPOSITES SCIENCE AND TECHNOLOGY, 2001, 61 (13) :1899-1912
[38]   On the elastic properties of carbon nanotube-based composites: modelling and characterization [J].
Thostenson, ET ;
Chou, TW .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2003, 36 (05) :573-582
[39]   Thermomechanical constitutive model of shape memory polymer [J].
Tobushi, H ;
Okumura, K ;
Hayashi, S ;
Ito, N .
MECHANICS OF MATERIALS, 2001, 33 (10) :545-554