VPO catalyst for n-butane oxidation to maleic anhydride:: A goal achieved, or a still open challenge?

被引：100
作者：
Ballarini, N.
Cavani, F.
Cortelli, C.
Ligi, S.
Pierelli, F.
Trifiro, F.
Fumagalli, C.
Mazzoni, G.
Monti, T.
机构：
[1] INSTM, Res Unit Bologna, Dipartimento Chim Ind & Mat, I-40136 Bologna, Italy
[2] Lonza SpA, I-24020 Scanzorosciate, BG, Italy
来源：
TOPICS IN CATALYSIS | 2006年 / 38卷 / 1-3期
关键词：
vanadyl pyrophosphate; n-butane; selective oxidation; maleic anhydride;
D O I：
10.1007/s11244-006-0080-z
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
This review describes recent findings in the oxidation of n-butane to maleic anhydride. The process is commercial since the 80's, but yet the yield is far from being optimised. Therefore, it represents an emblematic example of how several scientific disciplines, from solid-state science to reactor technology, can contribute to the improvement of the process performance.
引用
收藏
页码：147 / 156
页数：10
相关论文
共 157 条
[1]   EVOLUTION OF A VPO CATALYST IN N-BUTANE OXIDATION REACTION DURING THE ACTIVATION TIME [J].
ABON, M ;
BERE, KE ;
TUEL, A ;
DELICHERE, P .
JOURNAL OF CATALYSIS, 1995, 156 (01) :28-36
[2]   Correlation with the redox V5+/V4+ ratio in vanadium phosphorus oxide catalysts for mild oxidation of n-butane to maleic anhydride [J].
Abon, M ;
Herrmann, JM ;
Volta, JC .
CATALYSIS TODAY, 2001, 71 (1-2) :121-128
[3]   A MOLECULAR-LEVEL MECHANISM OF N-BUTANE OXIDATION TO MALEIC-ANHYDRIDE OVER VANADYL PYROPHOSPHATE [J].
AGASKAR, PA ;
DECAUL, L ;
GRASSELLI, RK .
CATALYSIS LETTERS, 1994, 23 (3-4) :339-351
[4]   Selective oxidation of n-butane to maleic anhydride on vanadyl pyrophosphate - II. Characterization of the oxygen-treated catalyst by electrical conductivity, Raman, XPS, and NMR spectroscopic techniques [J].
Ait-Lachgar, K ;
Tuel, A ;
Brun, M ;
Herrmann, JM ;
Krafft, JM ;
Martin, JR ;
Volta, JC ;
Abon, M .
JOURNAL OF CATALYSIS, 1998, 177 (02) :224-230
[5]   Selective oxidation of n-butane to maleic anhydride on vanadyl pyrophosphate .1. Influence of oxidation pretreatments on the catalytic performances [J].
AitLachgar, K ;
Abon, M ;
Volta, JC .
JOURNAL OF CATALYSIS, 1997, 171 (02) :383-390
[6]   A comparison of the reactivity of ''nonequilibrated'' and ''equilibrated'' V-P-O catalysts: Structural evolution, surface characterization, and reactivity in the selective oxidation of n-butane and n-pentane [J].
Albonetti, S ;
Cavani, F ;
Trifiro, F ;
Venturoli, P ;
Calestani, G ;
Granados, ML ;
Fierro, JLG .
JOURNAL OF CATALYSIS, 1996, 160 (01) :52-64
[7]  
Albonetti S, 2002, STUD SURF SCI CATAL, V143, P963
[8]   Butane partial oxidation in an externally fluidized bed-membrane reactor [J].
Alonso, M ;
Lorences, MJ ;
Pina, MP ;
Patience, GS .
CATALYSIS TODAY, 2001, 67 (1-3) :151-157
[9]  
Arpentinier P., 2001, TECHNOLOGY CATALYTIC
[10]   Simple chemical processes based on low molecular-mass alkanes as chemical feedstocks [J].
Baerns, M ;
Buyevskaya, O .
CATALYSIS TODAY, 1998, 45 (1-4) :13-22
12345678910