Magnetism in FeO at megabar pressures from X-ray emission spectroscopy

被引:146
作者
Badro, J
Struzhkin, VV
Shu, JF
Hemley, RJ
Mao, HK
Kao, CC
Rueff, JP
Shen, GY
机构
[1] Carnegie Inst Washington, Geophys Lab, Washington, DC 20015 USA
[2] Carnegie Inst Washington, Ctr High Pressure Res, Washington, DC 20015 USA
[3] Brookhaven Natl Lab, Natl Synchrotron Light Source, Upton, NY 11973 USA
[4] Univ Chicago, GSECARS, Chicago, IL 60637 USA
关键词
D O I
10.1103/PhysRevLett.83.4101
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We report evidence for a preserved magnetic state in FeO up to 143 GPa at room temperature using high-resolution x-ray emission spectroscopy. This observation is based on the spectral line shape of the Fe K beta emission line. Up to the highest pressure, FeO remains a magnetic insulator. Combining our results with previous Mossbauer data, we present a new magnetic phase diagram of FeO. Features like a closed-loop P-T antiferromagnetic domain confirm that high-pressure investigations can reveal new physical properties and unexpected phenomena.
引用
收藏
页码:4101 / 4104
页数:4
相关论文
共 23 条
[1]  
[Anonymous], 1990, METAL INSULATOR TRAN
[2]   Chemical dependence of interatomic X-ray transition energies and intensities -: a study of Mn Kβ" and Kβ2,5 spectra [J].
Bergmann, U ;
Horne, CR ;
Collins, TJ ;
Workman, JM ;
Cramer, SP .
CHEMICAL PHYSICS LETTERS, 1999, 302 (1-2) :119-124
[3]   Magnetic collapse in transition metal oxides at high pressure: Implications for the Earth [J].
Cohen, RE ;
Mazin, II ;
Isaak, DG .
SCIENCE, 1997, 275 (5300) :654-657
[4]  
ENG PJ, 1998, SPIE P, V3449, P145
[5]   Inverse versus normal NiAs structures as high-pressure phases of FeO and MnO [J].
Fang, Z ;
Terakura, K ;
Sawada, H ;
Miyazaki, T ;
Solovyev, I .
PHYSICAL REVIEW LETTERS, 1998, 81 (05) :1027-1030
[6]   First-principles study on electronic structures and phase stability of MnO and FeO under high pressure [J].
Fang, Z ;
Solovyev, IV ;
Sawada, H ;
Terakura, K .
PHYSICAL REVIEW B, 1999, 59 (02) :762-774
[7]   IN-SITU DETERMINATION OF THE NIAS PHASE OF FEO AT HIGH-PRESSURE AND TEMPERATURE [J].
FEI, YW ;
MAO, HK .
SCIENCE, 1994, 266 (5191) :1678-1680
[8]   X-ray imaging of stress and strain of diamond, iron, and tungsten at megabar pressures [J].
Hemley, RJ ;
Mao, HK ;
Shen, GY ;
Badro, J ;
Gillet, P ;
Hanfland, M ;
Hausermann, D .
SCIENCE, 1997, 276 (5316) :1242-1245
[9]  
HU J, IN PRESS
[10]   PHASE-STABILITY OF WUSTITE AT HIGH-PRESSURE FROM 1ST-PRINCIPLES LINEARIZED AUGMENTED PLANE-WAVE CALCULATIONS [J].
ISAAK, DG ;
COHEN, RE ;
MEHL, MJ ;
SINGH, DJ .
PHYSICAL REVIEW B, 1993, 47 (13) :7720-7731