Catalysis of phosphodiester transesterification by dinuclear Cu(II) complexes: The role of the second Cu(II) ion

被引：44
|
作者：
Liu, SH [1 ]
Hamilton, AD [1 ]
机构：
[1] UNIV PITTSBURGH, DEPT CHEM, PITTSBURGH, PA 15260 USA
来源：
BIOORGANIC & MEDICINAL CHEMISTRY LETTERS | 1997年 / 7卷 / 13期
基金：
美国国家卫生研究院;
关键词：
D O I：
10.1016/S0960-894X(97)00303-X
中图分类号：
R914 [药物化学];
学科分类号：
100701 ;
摘要：
Two novel dinuclear Cu(II) complexes are prepared and shown to be highly active catalysts for phosphodiester transesterification. Comparative studies on the dinuclear complexes and corresponding mononuclear complexes reveal that one dinuclear complex achieves high activity by double Lewis acid and double general base catalysis while the other exploits single Lewis acid and double general base catalysis. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码：1779 / 1784
页数：6
相关论文
共 50 条
  • [1] Catalysis of phosphodiester transesterification by Cu(II)-terpyridine complexes with peripheral pendent base groups: Implications for the mechanism
    Liu, SH
    Hamilton, AD
    TETRAHEDRON LETTERS, 1997, 38 (07) : 1107 - 1110
  • [2] Metallomicellar catalysis: Hydrolysis of phosphodiester with Cu(II) and Zn(II) complexes in micellar solution
    Du, J
    Chen, MZ
    Wu, YR
    Zeng, XC
    Liu, YJ
    Shunzo, Y
    Yoshimi, S
    JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY, 2003, 24 (05) : 683 - 689
  • [3] Hydrolysis of phosphodiester with hydroxo- or carboxylate-bridged dinuclear Ni(II) and Cu(II) complexes
    Yamaguchi, K
    Akagi, F
    Fujinami, S
    Suzuki, M
    Shionoya, M
    Suzuki, S
    CHEMICAL COMMUNICATIONS, 2001, (04) : 375 - 376
  • [4] Cyano bridged dinuclear Cu(II) complexes
    Parker, RJ
    Spiccia, L
    Moubaraki, B
    Murray, KS
    Skelton, BW
    White, AH
    INORGANICA CHIMICA ACTA, 2000, 300 (300-302) : 922 - 931
  • [5] Mechanochemical synthesis and catalysis of dinuclear Cu (II) complexes in C-S coupling
    Guo, Zhenwei
    Fei, Zhenduo
    Hao, Xiujia
    Feng, Daming
    Guo, Fang
    APPLIED ORGANOMETALLIC CHEMISTRY, 2024, 38 (11)
  • [6] Metallomicellar catalysis: Hydrolysis of phosphate monoester and phosphodiester by Cu(II), Zn(II) complexes of pyridyl ligands in CTAB micellar solution
    Jiang, Fubin
    Huang, Liya
    Meng, Xiangguang
    Du, Juan
    Yu, Xiaoqi
    Zhao, Yufen
    Zeng, Xiancheng
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2006, 303 (01) : 236 - 242
  • [7] CU(II) ION INTERACTIONS WITH DRUGS - TERNARY COMPLEXES OF CU(II) ION WITH CIMETIDINE AND PHENOBARBITAL
    ORTIZ, R
    BORRAS, J
    PERELLO, L
    JIMENEZ, H
    SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1985, 15 (08): : 991 - 1003
  • [8] Hydrolysis of phosphodiester catalyzed by analogous dinuclear Cu(II) complex in CTAB micellar solution
    Cheng Si-Qing
    Wang You-Rong
    Yan Jian-Fang
    Zeng Xiancheng
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2007, 292 (01) : 32 - 35
  • [9] Synthesis, Characterization and Biochemical Activity of Dinuclear Cu(II)/Ni(II)/Co(II) and Tetranuclear Cu(II) Complexes of Schiff Base
    Karabocek, Nevin
    Eski, Pinar
    Baskan, Oya
    Karabocek, Serdar
    ASIAN JOURNAL OF CHEMISTRY, 2012, 24 (01) : 387 - 390
  • [10] Metallomicellar catalysis: Phosphodiester hydrolysis catalyzed by Cu(II), Zn(II), Ni(II), and Co(II) complexes of chelating pyridyl donor ligands in CTAB micellar solution
    Meng, Y
    Jiang, FB
    Hu, W
    Meng, XG
    Yu, XQ
    Zeng, XC
    JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY, 2006, 27 (01) : 15 - 21
12345