Acidic ionic liquids: Promising and cost-effective solvents for processing lignocellulosic biomass

被引:97
作者
Asim, Azmat Mehmood [1 ]
Uroos, Maliha [1 ]
Naz, Sadia [1 ]
Sultan, Misbah [1 ]
Griffin, Gregory [2 ]
Muhammad, Nawshad [3 ]
Khan, Amir Sada [4 ]
机构
[1] Univ Punjab, Inst Chem, Lahore 54000, Pakistan
[2] RMIT Univ, Chem Engn, Sch Engn, 124 La Trobe St, Melbourne, Vic 3000, Australia
[3] COMSATS Univ Islamabad, IRCBM, Lahore Campus, Lahore 54600, Pakistan
[4] Univ Sci & Technol, Dept Chem, Bannu 2810, Kpk, Pakistan
关键词
Acidic ionic liquids; Biomass processing; Platform chemicals; Recyclability; Cost effectiveness; LEVULINIC ACID; ENZYMATIC-HYDROLYSIS; EFFICIENT CONVERSION; CATALYTIC CONVERSION; HYDROGEN SULFATE; PHYSICOCHEMICAL PROPERTIES; THERMOPHYSICAL PROPERTIES; STRUCTURAL-PROPERTIES; SELECTIVE CONVERSION; FURFURAL PRODUCTION;
D O I
10.1016/j.molliq.2019.110943
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The efficacy of ionic liquids in pretreatment and production of renewable or platform chemicals from lignocellulosic biomass have been substantiated by many research studies. The search for more efficient, low cost and less toxic ionic liquids is still an active research subject. Acidic ionic liquids (Ms) are a type of IL which has emerged as very attractive pretreatment solvents. This review described the recent developments on biomass processing ability and efficiency of different Ails. Different influential process variables are also look over for their impact on biomass pretreatment, deconstruction and yields of various targeted platform chemicals i.e. 5-hydroxymethylfurfural (5-HMF), levulinic acid (LA) etc., total Reducing Sugars (TRS) and depolymerized products of lignin. The review also highlights the associated problems of ionic liquids i.e. challenges in utilization for the biorefinery, stability, recycling and environmental hazards, that faces in its utilization for biomass processing. The cost is a key factor in any chemical process, therefore, an overview of the cost-effectiveness of AILS have been provided. (C) 2019 Elsevier B.V. All rights reserved.
引用
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页数:16
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