A High-Performance Recycling Solution for Polystyrene Achieved by the Synthesis of Renewable Poly( thioether) Networks Derived from d-Limonene

被引：42

作者：

Hearon, Keith ^{[1
]}

Nash, Landon D. ^{[1
]}

Rodriguez, Jennifer N. ^{[1
]}

Lonnecker, Alexander T. ^{[2
]}

Raymond, Jeffery E. ^{[2
]}

Wilson, Thomas S. ^{[3
]}

Wooley, Karen L. ^{[2
]}

Maitland, Duncan J. ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Biomed Engn, College Stn, TX 77843 USA

[2] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA

[3] Lawrence Livermore Natl Lab, Div Chem Sci, Livermore, CA 94550 USA

来源：

ADVANCED MATERIALS | 2014年 / 26卷 / 10期

基金：

美国国家科学基金会; 美国国家卫生研究院;

关键词：

renewable polymers; recycling; nanocomposites; thiol-ene click chemistry; POLYMERIZATION; CHEMISTRY; POLYMERS; SOLVENT;

D O I：

10.1002/adma.201304370

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Nanocomposite polymers are prepared using a new sustainable materials synthesis process in which d-Limonene functions simultaneously both as a solvent for recycling polystyrene (PS) waste and as a monomer that undergoes UV-catalyzed thiol-ene polymerization reactions with polythiol comonomers to afford polymeric products composed of precipitated PS phases dispersed throughout elastomeric poly(thioether) networks. These blended networks exhibit mechanical properties that greatly exceed those of either polystyrene or the poly(thioether) network homopolymers alone. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1552 / 1558

页数：7

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