Model studies examining the use of dicyclohexylphenylphosphine to enhance the oxidative and thermal stability of future jet fuels

被引:21
作者
Beaver, BD [1 ]
Gao, L
Fedak, MG
Coleman, MM
Sobkowiak, M
机构
[1] Duquesne Univ, Dept Chem & Biochem, Pittsburgh, PA 15282 USA
[2] Penn State Univ, Energy Inst, University Pk, PA 16802 USA
关键词
D O I
10.1021/ef020028r
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
A model study is described that tests the feasibility of using dicyclohexylphenylphosphine (DCP) as an additive to provide oxidative stability for future jet fuels. In addition, the mechanism of autoxidation of DCP in dodecane is examined.
引用
收藏
页码:1134 / 1140
页数:7
相关论文
共 32 条
[1]   Radiolytic studies of the mechanism of autoxidation of triphenylphosphine and related compounds [J].
Alfassi, ZB ;
Neta, P ;
Beaver, B .
JOURNAL OF PHYSICAL CHEMISTRY A, 1997, 101 (11) :2153-2158
[2]  
Beaver B, 1998, HETEROATOM CHEM, V9, P133, DOI 10.1002/(SICI)1098-1071(1998)9:2<133::AID-HC6>3.0.CO
[3]  
2-D
[4]   Model studies directed at the development of new thermal oxidative stability enhancing additives for future jet fuels [J].
Beaver, B ;
DeMunshi, R ;
Heneghan, SP ;
Whitacre, SD ;
Neta, P .
ENERGY & FUELS, 1997, 11 (02) :396-401
[5]  
BEAVER BD, 1995, 5 INT C STAB HANDL L, P241
[6]   SOME UNRESOLVED PROBLEMS IN OXIDATION AND COMBUSTION [J].
BENSON, SW ;
NANGIA, PS .
ACCOUNTS OF CHEMICAL RESEARCH, 1979, 12 (07) :223-228
[7]   PHOSPHORANYL RADICALS - THEIR STRUCTURE, FORMATION, AND REACTIONS [J].
BENTRUDE, WG .
ACCOUNTS OF CHEMICAL RESEARCH, 1982, 15 (04) :117-125
[8]   AUTOXIDATION OF TRIALKYLPHOSPHINES [J].
BUCKLER, SA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1962, 84 (16) :3093-&
[9]   FORMATION OF RADICALS IN THE MITSUNOBU REACTION [J].
CAMP, D ;
HANSON, GR ;
JENKINS, ID .
JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (10) :2977-2980
[10]  
COLEMAN MM, 1998, PREPR PAP AM CHEM SO, V43, P353