Effect of heat treatment on physical properties of CdO films deposited by sol-gel method

被引：95

作者：

Aksoy, Seval ^{[1
]}

Caglar, Yasemin ^{[1
]}

Ilican, Saliha ^{[1
]}

Caglar, Mujdat ^{[1
]}

机构：

[1] Anadolu Univ, Fac Sci, Dept Phys, TR-26470 Eskisehir, Turkey

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2009年 / 34卷 / 12期

关键词：

CdO; Sol-gel method; Crystal structure; Optical band gap; THIN-FILMS; CADMIUM-OXIDE; OPTICAL-PROPERTIES;

D O I：

10.1016/j.ijhydene.2008.09.057

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

CdO film has been deposited by sol-gel spin coating method on the glass substrate and then the film has been annealed at 400, 500, 600 degrees C for 1 h. Effect of annealing temperature on the structural and optical properties of the film has been investigated. The crystal structure and orientation of the as-grown and annealed CdO films have been investigated by X-ray diffraction method. Annealed CdO films are polycrystalline with (111) preferential orientation. The information on strain and grain size is obtained from the full width-at-half-maximum (FWHM) of the diffraction peaks. Texture coefficient and lattice constant have been calculated. The surface morphology of the films has been analyzed. The optical band gap value decreased with increasing the annealing temperatures. (c) 2008 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.

引用

页码：5191 / 5195

页数：5

共 17 条

[1]

[Anonymous], 1940, CHEM ED, DOI DOI 10.1021/ED018P249.1

[2] Single-crystalline rocksalt CdO layers grown on GaAs(001) substrates by metalorganic molecular-beam epitaxy [J].

Ashrafi, ABMA ;

Kumano, H ;

Suemune, I ;

Ok, YW ;

Seong, TY .

APPLIED PHYSICS LETTERS, 2001, 79 (04) :470-472

[3]

Barret C.S., 1980, STRUCTURE METALS

[4] OPTIMIZATION OF CDO LAYER IN A SE-CDO PHOTOVOLTAIC CELL [J].

CHAMPNESS, CH ;

CHAN, CH .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 1995, 37 (01) :75-92

[5] Oxygen partial pressure dependence of the structural properties of CdO thin films deposited by a modified reactive vacuum evaporation process [J].

Eze, FC .

MATERIALS CHEMISTRY AND PHYSICS, 2005, 89 (2-3) :205-210

[6] Effect of fluorine doping on semiconductor to metal-like transition and optical properties of cadmium oxide thin films deposited by sol-gel process [J].

Ghosh, P ;

Das, S ;

Kundoo, S ;

Chattopadhyay, K .

JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2005, 34 (02) :173-179

[7] CHARACTERIZATION OF TRANSPARENT CONDUCTING CDO FILMS DEPOSITED BY SPRAY-PYROLYSIS [J].

GURUMURUGAN, K ;

MANGALARAJ, D ;

NARAYANDASS, SK ;

SEKAR, K ;

VALLABHAN, CPG .

SEMICONDUCTOR SCIENCE AND TECHNOLOGY, 1994, 9 (10) :1827-1832

[8] Magnetron sputtered transparent conducting CdO thin films [J].

Gurumurugan, K ;

Mangalaraj, D ;

Narayandass, SAK .

JOURNAL OF ELECTRONIC MATERIALS, 1996, 25 (04) :765-770

[9] DC reactive magnetron sputtered CdO thin films [J].

Gurumurugan, K ;

Mangalaraj, D ;

Narayandass, SK ;

Nakanishi, Y .

MATERIALS LETTERS, 1996, 28 (4-6) :307-312

[10] DISORDER AND OXYGEN TRANSPORT IN CADMIUM OXIDE [J].

HAUL, R ;

JUST, D .

JOURNAL OF APPLIED PHYSICS, 1962, 33 (01) :487-&

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