Synthesis of [2]rotaxanes by the catalytic reactions of a macrocyclic copper complex

被引：99
作者：
Saito, Shinichi [1 ]
Takahashi, Eiko [1 ]
Nakazono, Kazuko [1 ]
机构：
[1] Tokyo Univ Sci, Dept Chem, Fac Sci, Shinjuku Ku, Tokyo 1628601, Japan
来源：
ORGANIC LETTERS | 2006年 / 8卷 / 22期
关键词：
D O I：
10.1021/ol062247s
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
We synthesized [2] rotaxanes by the reactions catalyzed by a macrocyclic Cu(I)-phenanthroline complex. The catalytic site was located inside the ring component so that the rotaxane could be selectively formed. A C-S bond-forming reaction and oxidative dimerization of alkyne was utilized for the efficient synthesis of a new series of [2] rotaxanes.
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页码：5133 / 5136
页数：4
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