Transition-Metal-Catalyzed Enantioselective [2+2+2] Cycloadditions for the Synthesis of Axially Chiral Biaryls

被引：332
作者：
Tanaka, Ken [1 ]
机构：
[1] Tokyo Univ Agr & Technol, Dept Appl Chem, Grad Sch Engn, Tokyo, Japan
来源：
CHEMISTRY-AN ASIAN JOURNAL | 2009年 / 4卷 / 04期
基金：
日本科学技术振兴机构;
关键词：
cycloaddition; asymmetric catalysis; axial chirality; biaryls; transition metals; ONE-STEP SYNTHESIS; REGIOSELECTIVE INTERMOLECULAR CYCLOTRIMERIZATION; RHODIUM(I)/BINAP-TYPE BISPHOSPHINE COMPLEXES; CATIONIC RHODIUM(I)/MODIFIED BINAP; ACTIVE ATROPISOMERIC ANILIDES; C-N AXES; ASYMMETRIC-SYNTHESIS; ALKYNE CYCLOTRIMERIZATION; ORGANIC-SYNTHESIS; CROSS-CYCLOTRIMERIZATION;
D O I：
10.1002/asia.200800378
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Recent advances towards a development of novel transition-metal-catalyzed enantioselective [2+2+2] cycloadditions for the synthesis of axially chiral biaryls are reviewed. A number of efficient enantioselective biaryl syntheses were accomplished by chiral cobalt(I), iridium(I), and rhodium(I) complex catalyzed [2+2+2] cycloadditions. Furthermore, the enantioselective synthesis of axially chiral biaryls possessing non-biaryl axial chirality was also developed by using chiral rhodium(I) complexes as catalysts.
引用
收藏
页码：508 / 518
页数：11
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