Novel Nanocomposite Hydrogels Consisting of Layered Double Hydroxide with Ultrahigh Tensibility and Hierarchical Porous Structure at Low Inorganic Content

被引:301
作者
Hu, Ziqiao [1 ]
Chen, Guangming [1 ]
机构
[1] Chinese Acad Sci, Inst Chem, BNLMS, Beijing 100190, Peoples R China
基金
中国国家自然科学基金;
关键词
DOUBLE-NETWORK HYDROGELS; MECHANICAL-PROPERTIES; COMPOSITE HYDROGELS; THERMAL-STABILITY; CRACK TIPS; CLAY; POLY(ETHYLENE-TEREPHTHALATE); PHOTOLUMINESCENCE; POLYMERIZATION; TRANSITION;
D O I
10.1002/adma.201400179
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel type of polymer nanocomposite (NC) hydrogel with extraordinary mechanical properties at low inorganic content is prepared and investigated. The NC hydrogels consist of isethionate-loaded layered double hydroxide/polyacrylamide (LDH-Ise/PAM) - with LDH-Ise being used because of its swelling properties and no conventional organic crosslinker. The NC hydrogels exhibit an unusual hierarchical porous structure at the micro- and nanometer scales, and their elongation at break can exceed 4000%.
引用
收藏
页码:5950 / +
页数:8
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