Two new octamolybdate-based hybrids constructed by dinuclear/tetranuclear metal-tetrazole clusters: Syntheses, structures and photoluminescence

被引：12

作者：

Shi, Zhenyu ^{[1
,2
]}

Peng, Jun ^{[1
]}

Yu, Xia ^{[1
]}

Zhang, Zheyu ^{[1
]}

Wang, Xiang ^{[1
]}

Zhou, Wanli ^{[1
]}

机构：

[1] NE Normal Univ, Dept Chem, Key Lab Polyoxometalate Sci, Minist Educ, Changchun 130024, Jilin, Peoples R China

[2] Xingyi Normal Coll Nationalities, Xingyi 562400, Guizhou, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2014年 / 41卷

基金：

美国国家科学基金会;

关键词：

Octamolybdate; Hydrothermal synthesis; Hybrid; Tetrazole; ORGANIC FRAMEWORKS; TUNABLE PLATFORM; LIGAND;

D O I：

10.1016/j.inoche.2014.01.002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Through hydrothermal reactions of d(0) metal ions with 5-(4-imidazol-1-yl-phenyl)-2H-tetrazole (HL), two new octamolybdate-based hybrids, namely, (H2L)(2)[Ag-2(HL)(2)([beta-Mo8O26)] (1) and [Cu-4(HL)(4)(theta-Mo8O26)]center dot 5H(2)O (2), have been prepared and structurally characterized. X-ray single-crystal analyses show that compound 1 consists of discrete H2L cations and infinite one-dimensional (1D) anionic chains [Ag-2(HL)(2)(beta-Mo8O26)](2-) constructed by [beta-Mo8O26](4-) bridged via dinuclear clusters (Ag-2(HL)(2))(2+). Compound 2 displays a 2D network generated by 1D cationic tetranuclear copper cluster chains (Cu-4(HL)(4)}. and theta-Mo8O26](4-) clusters. In addition, luminescent properties of both compounds have been studied. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：84 / 87

页数：4

共 28 条

[1] Metal-organic frameworks for upgrading biogas via CO2 adsorption to biogas green energy [J].