Comparison of photoinduced electron transfer reactions of C-60 and aromatic carbonyl compounds

被引：8
|
作者：
Fukuzumi, S
机构：
[1] Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita
来源：
RESEARCH ON CHEMICAL INTERMEDIATES | 1997年 / 23卷 / 06期
关键词：
D O I：
10.1163/156856797X00213
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The one-electron reduction potential of the triplet excited state of C-60 is similar to those of some aromatic carbonyl compounds. Thus, photoinduced electron transfer is expected to occur from the common electron donors to both C-60 and aromatic carbonyl compounds. In this paper comparison is made between photoinduced electron transfer from organosilanes and organostannanes used as the electron donors to the triplet excited states of C-60 and aromatic carbonyl compounds, providing valuable insight into their common mechanistic features for the C-C bond formation via photoinduced electron transfer as well as the new functionalization method of C-60.
引用
收藏
页码：519 / 539
页数：21
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