Magnetostructural examination of Mn(III) complexes [Mn(cyclam)X2]+ with strong axial ligands

被引：4
|
作者：
Baba, Haruyuki [1 ]
Nakano, Motohiro [1 ]
机构：
[1] Osaka Univ, Grad Sch Engn, Div Appl Chem, Suita, Osaka 5650871, Japan
来源：
POLYHEDRON | 2009年 / 28卷 / 9-10期
关键词：
Magnetic anisotropy; Ligand field; Angular-overlap model (AOM); Manganese(III); SINGLE-MOLECULE MAGNETS; HIGH-SPIN MOLECULES; MANGANESE(III) COMPLEXES; METAL-IONS; MAGNETIZATION; REDUCTION; CROSSOVER; TRANSITION; PARAMETERS; IRON(III);
D O I：
10.1016/j.poly.2009.02.013
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three novel Mn(III) cyclam complexes, [Mn(cyclam)(NCBH3)(2)](CF3SO3), [Mn(cyclam)(NCBPh3)(2)](CF3SO3), and [Mn(cyclam)(NCSe)(2)](CF3SO3) center dot H2O, have been synthesized. These complexes are in the high-spin state between 4 and 350 K, and show large zero-field splittings. The crystal structure of [Mn(cyclam)(NCBH3)(2)](CF3SO3) was determined where the axial elongation of Mn-N bonds is found to be the largest among the homologue complexes. Ligand field in the [Mn(cyclam)X-2](+) complex series was examined by angular-overlap model calculation. (c) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2087 / 2091
页数：5
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