Nanofibrillated cellulose (CNF) from eucalyptus sawdust as a dry strength agent of unrefined eucalyptus handsheets

被引:85
作者
Evangelina Vallejos, Maria [1 ,2 ]
Esteban Felissia, Fernando [1 ]
Cristina Area, Maria [1 ,2 ]
Vanesa Ehman, Nanci [1 ,2 ]
Tarres, Quim [3 ]
Mutje, Pere [3 ]
机构
[1] IMAM UNaM CONICET, Programa Celulosa & Papel, Inst Mat Misiones, RA-3300 Posadas, Misiones, Argentina
[2] Consejo Nacl Invest Cient & Tecn, Caba, Argentina
[3] Univ Girona, Dept Ingn Quim, Grp Invest LEPAMAP, Girona 17071, Spain
关键词
Biorefinery; Eucalyptus sawdust; Nanofibrillated cellulose; Papermaking; Surface addition; Wet strength additive; TEMPO-MEDIATED OXIDATION; NATIVE CELLULOSE; FIBRILLATED CELLULOSE; PAPER; PULP; NANOFIBERS; NANOPAPER;
D O I
10.1016/j.carbpol.2015.12.004
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Nanofibrillated cellulose has been obtained from the cellulosic fraction of eucalyptus sawdust. The fractionation process involved the partial removal of hemicelluloses and lignin. CNF was obtained using TEMPO oxidation with NaOCl in basic medium followed by mechanical homogenization. The obtained CNF was subsequently used as a dry strength agent on unbleached unrefined eucalyptus pulp. The addition of 3, 6 and 9 wt.% of CNF increased lineally the tensile index of handsheets to about 55 N m g(-1) at 35 SR, compatible with papermachine runnability. The other mechanical properties also increased substantially, and porosity decreased moderately. The estimated specific surface and average diameter of these CNF were 60 m(2) g(-1), and of 41.0 nm, respectively. The addition of 9 wt.% of CNF produced an increase in mechanical strength, equivalent to that produced by PFI refining at 1600 revolutions. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:99 / 105
页数:7
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