Sensitive recognition of cyanide through supramolecularly complexed new calix[4]arenes

被引：14
作者：
Chawla, Har Mohindra [1 ]
Shukla, Richa [1 ]
Goel, Preeti [1 ]
机构：
[1] Indian Inst Technol Delhi, Dept Chem, New Delhi 110016, India
来源：
NEW JOURNAL OF CHEMISTRY | 2014年 / 38卷 / 11期
关键词：
FLUORESCENT SENSOR; CHEMOSENSOR; ENSEMBLE; CALIXARENES; DESIGN; PROBE; IONS;
D O I：
10.1039/c4nj00065j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two new calix[4]arene based fluorescence sensors (L1 and L2) have been synthesized and characterized. L1 was found to selectively quench fluorescence intensity upon addition of Cu2+ ions through host-guest complexation and display "on-off'' behavior while L2 was not that efficient. The in situ generated L1.Cu2+ complex could further recognize CN- from the anionic broth with a distinct "off-on'' behavior in the fluorescence titration.
引用
收藏
页码：5264 / 5267
页数：4
相关论文
共 35 条
[1]   Synthesis and antimicrobial activity of succinimido(2-aryl-4-oxo-3{[( quinolin-8-yloxy)acetyl]amino}-1,3-thiazolidin-5-yl)acetates [J].
Ahmed, Maqbool ;
Sharma, Ranjana ;
Nagda, Devendra P. ;
Jat, Jawahar L. ;
Talesara, Ganpat L. .
ARKIVOC, 2006, :66-75
[2]  
[Anonymous], 1999, ULLMANNS ENCY IND CH
[3]  
[Anonymous], 2021, Consumption of water for drinking and other use ENE3VND
[4]   Neutral anion receptors: design and application [J].
Antonisse, MMG ;
Reinhoudt, DN .
CHEMICAL COMMUNICATIONS, 1998, (04) :443-448
[5]  
Baird C.i Cann., 2005, Environmental chemistry
[6]  
Beer PD, 2001, ANGEW CHEM INT EDIT, V40, P486, DOI 10.1002/1521-3773(20010202)40:3<486::AID-ANIE486>3.3.CO
[7]  
2-G
[8]   Aggregates of a triphenylene based chemosensing ensemble for sensitive detection of cyanide ions in an aqueous medium [J].
Bhalla, Vandana ;
Arora, Harshveer ;
Kumar, Manoj .
DALTON TRANSACTIONS, 2013, 42 (13) :4450-4455
[9]  
Bhattacharya R, 2009, HANDBOOK OF TOXICOLOGY OF CHEMICAL WARFARE AGENTS, P255, DOI 10.1016/B978-0-12-374484-5.00019-5
[10]  
Chawla H., 2010, Chemical Sensors Fundamentals of Sensing Materials, P300
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