Particle suspension reactors and materials for solar-driven water splitting

被引：356

作者：

Fabian, David M. ^{[1
]}

Hu, Shu ^{[2
]}

Singh, Nirala ^{[3
]}

Houle, Frances A. ^{[4
]}

Hisatomi, Takashi ^{[5
]}

Domen, Kazunari ^{[5
]}

Osterlohf, Frank E. ^{[6
]}

Ardo, Shane ^{[1
,7
]}

机构：

[1] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA

[2] CALTECH, Joint Ctr Artificial Photosynth, Pasadena, CA 91125 USA

[3] Univ Calif Santa Barbara, Dept Chem Engn, Santa Barbara, CA 93106 USA

[4] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Joint Ctr Artificial Photosynth, Berkeley, CA 94720 USA

[5] Univ Tokyo, Dept Chem Syst Engn, Tokyo 1138656, Japan

[6] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA

[7] Univ Calif Irvine, Dept Chem Engn & Mat Sci, Irvine, CA 92697 USA

来源：

ENERGY & ENVIRONMENTAL SCIENCE | 2015年 / 8卷 / 10期

基金：

美国国家科学基金会; 日本学术振兴会;

关键词：

VISIBLE-LIGHT IRRADIATION; MODIFIED-TAON PHOTOCATALYSTS; SHUTTLE REDOX MEDIATOR; Z-SCHEME PHOTOCATALYST; HYDROGEN-PRODUCTION; SOLID-SOLUTION; 2-STEP PHOTOEXCITATION; ENERGY-CONVERSION; ELECTRON MEDIATOR; OXYGEN-EVOLUTION;

D O I：

10.1039/c5ee01434d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reactors based on particle suspensions for the capture, conversion, storage, and use of solar energy as H-2 are projected to be cost-competitive with fossil fuels. In light of this, this review paper summarizes state-of-the-art particle light absorbers and cocatalysts as suspensions (photocatalysts) that demonstrate visible-light-driven water splitting on the laboratory scale. Also presented are reactor descriptions, theoretical considerations particular to particle suspension reactors, and efficiency and performance characterization metrics. Opportunities for targeted research, analysis, and development of reactor designs are highlighted.

引用

页码：2825 / 2850

页数：26

共 170 条

[1] Photocatalytic overall water splitting under visible light by TaON and WO3 with an IO3 -/I- shuttle redox mediator [J].