Oxidation of Ni electrode in BaTiO3 based multilayer ceramic capacitor (MLCC)

被引：28

作者：

Lin, C. C. ^{[1
]}

Wei, W. C. J. ^{[1
]}

Su, C. Y.

Hsueh, C. H. ^{[1
]}

机构：

[1] Natl Taiwan Univ, Inst Mat Sci & Engn, Taipei 10764, Taiwan

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2009年 / 485卷 / 1-2期

关键词：

Nickel; Electrode; Discontinuity; Oxidation; MLCC; RHOMBOHEDRAL DISTORTION; METAL ELECTRODE; HEAT-TREATMENT; NICKEL;

D O I：

10.1016/j.jallcom.2009.06.050

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

High temperature heat treatment of internal Ni electrode and BaTiO3 dielectric layers is one of the important steps in the sintering process of multilayer ceramic capacitors (MLCCs). In this study microstructural, analysis of partially oxidized Ni electrode in dielectric layers was conducted Sub-micrometric NiO scales. were found along the interface of Ni/BaTiO3. In addition, the capacitance, dielectric loss, and isolation resistances of the samples after post-treatment in N-2 atmosphere at 1000 degrees C for 0-8 h were analyzed A detailed analysis on the NiO and the discussion on the formation mechanism of NiO are presented in this paper. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：653 / 659

页数：7

共 20 条

[1] Re-oxidation of Ni-MLCs
Albertsen, K
[J]. JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2004, 24 (06) : 1883 - 1887
[2] BARSOUM MW, 2000, FUNDAMENTALS CERAMIC
[3] BIRK N, 1983, INTRO HIGH TEMPERATU
[4] The influence of crystallographic orientation of nickel surface on oxidation inhibition by ceria coatings
Czerwinski, F
Szpunar, JA
[J]. ACTA MATERIALIA, 1998, 46 (04) : 1403 - 1417
[5] Dielectric materials for sintering in reducing atmospheres
Hennings, DFK
[J]. JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2001, 21 (10-11) : 1637 - 1642
[6] Analyses of steady-state interface fracture of elastic multilayered beams under four-point bending
Hsueh, C. H.
Tuan, W. H.
Wei, W. C. J.
[J]. SCRIPTA MATERIALIA, 2009, 60 (08) : 721 - 724
[7] Interface microstructure between Ni base-metal electrode and BaTiO3 dielectric
Lee, Kun-Hsu
Wu, Yu-Chuan
Lu, Hong-Yang
[J]. JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2007, 40 (16) : 4902 - 4909
[8] Stress heterogeneity of thermally grown polycrystalline nickel oxide layers
Milhet, X
Cormier, J
Renault, PO
Coupeau, C
Colin, J
[J]. MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2005, 395 (1-2): : 22 - 26
[9] Oxidation of nickel and transport properties of nickel oxide
Mrowec, S
Grzesik, Z
[J]. JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2004, 65 (10) : 1651 - 1657
[10] Surface and subsurface oxide formation on Ni(100) and Ni(111)
Muñoz-Márquez, MA
Tanner, RE
Woodruff, DP
[J]. SURFACE SCIENCE, 2004, 565 (01) : 1 - 13

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