Reaction of [Et3NH][(μ-RE)(μ-CO)Fe2(CO)6] (E = S, Se) with azides.: Synthesis of (μ-RE)(μ-p-R1C6H4N3H)Fe2(CO)6 and crystal structure of (μ-ButS)(μ-PhN3H)Fe2(CO)6

被引：4

作者：

Wang, ZX ^{[1
]}

Miao, SB

Zhou, ZY

Zhou, XG

机构：

[1] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China

[2] Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2000年 / 601卷 / 01期

关键词：

iron; selenium; sulfur; triazenido ligand; complex; structure;

D O I：

10.1016/S0022-328X(00)00039-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of [Et3NH][(mu-RE)(mu-CO)Fe-2(CO)(6)] (E = S, Se) (1) with aryl azides gives bridging triazenido complexes (mu-RE)(mu-p-(RC6H4N3H)-C-1)Fe-2(CO)(6) (2-8) (2, RE = (BuS)-S-t, R-1 = H; 3, RE = PhS, R-1 = H; 4, RE = (BuS)-S-t, R-1 = Cl; 5, RE = (BuS)-S-t, R-1 = MeO; 6, RE = PhS, R-1 = MeO; 7, RE = PhSe, R-1 = H; 8, RE = PhSe, R-1 = Cl). These complexes were characterized by elemental analyses and H-1-NMR and IR spectroscopy. The structure of complex 2, established by single-crystal X-ray diffraction analysis, shows that the triazenido ligand binds to two iron centers in a bridging bidentate fashion. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：87 / 92

页数：6

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