Photoinduced effects in As-S-P glasses

被引:2
作者
Santagneli, Silvia Helena [1 ]
Messaddeq, Sandra Helena [1 ]
Lima Ribeiro, Sidney Jose [1 ]
Messaddeq, Younes [1 ]
机构
[1] UNESP, Inst Chem, BR-14800900 Araraquara, SP, Brazil
来源
PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS | 2009年 / 246卷 / 08期
基金
巴西圣保罗研究基金会;
关键词
AMORPHOUS-CHALCOGENIDE FILMS; IN-SITU MEASUREMENTS; THIN-FILMS; VOLUME CHANGES; AS2S3; GLASS; SYSTEM; PHOTO; SPECTRA;
D O I
10.1002/pssb.200982020
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
We report the photoinduced effects on the glass composition As2S3 and As29.6P7.4S63 when exposed to UV light. The morphology of the glass surface irradiated at different power densities was investigated by use of optical microscopy and scanning electron microscopy (SEM). A power density dependence on the photoexpansion (PE) and photoablation (PA) is observed. Raman measurement after irradiation shows the formation of As-O bonds in As29.6P7.4S63. Also, the appearance of P=O bonds indicate the incorporation of oxygen at the glass surface during the irradiation process. (C) 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
引用
收藏
页码:1866 / 1870
页数:5
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