Enhancement of guest-responsivity by mesocrystallization of porous coordination polymers

被引：8
作者：
Mishima, Akio [1 ]
Koshiyama, Tomomi [1 ]
Real, Jose A. [2 ]
Ohba, Masaaki [1 ]
机构：
[1] Kyushu Univ, Grad Sch Sci, Dept Chem, Nishi Ku, 744 Motooka, Fukuoka 8190395, Japan
[2] Univ Valencia, Inst Ciencia Mol ICMol, Paterna 46980, Spain
来源：
JOURNAL OF MATERIALS CHEMISTRY C | 2017年 / 5卷 / 15期
关键词：
METAL-ORGANIC FRAMEWORKS; SPIN-CROSSOVER COMPOUND; ROOM-TEMPERATURE; NANOCRYSTALLINE MATERIALS; TRANSITION-TEMPERATURE; PROTON CONDUCTION; HYDROGEN STORAGE; NANOPARTICLES; BISTABILITY; ADSORPTION;
D O I：
10.1039/c7tc00751e
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Mesocrystals of a porous coordination polymer {Fe(pz)[Pt(CN)(4)]} (1) showing spin transition were prepared by the reverse micelle method, and the size-controlled mesocrystal 1 kept its porous property and magnetic bistability and exhibited higher guest-responsivity with switching the spin state in both solid and aqueous suspension states than the bulk 1.
引用
收藏
页码：3706 / 3713
页数：8
相关论文
共 66 条
  • [1] Oxidative Addition of Halogens on Open Metal Sites in a Microporous Spin-Crossover Coordination Polymer
    Agusti, Gloria
    Ohtani, Ryo
    Yoneda, Ko
    Gaspar, Ana B.
    Ohba, Masaaki
    Sanchez-Royo, Juan F.
    Carmen Munoz, M.
    Kitagawa, Susumu
    Real, Jose A.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (47) : 8944 - 8947
  • [2] A Switchable Molecular Rotator: Neutron Spectroscopy Study on a Polymeric Spin-Crossover Compound
    Alberto Rodriguez-Velamazan, J.
    Gonzalez, Miguel A.
    Real, Jose A.
    Castro, Miguel
    Carmen Munoz, M.
    Gaspar, Ana B.
    Ohtani, Ryo
    Ohba, Masaaki
    Yoneda, Ko
    Hijikata, Yuh
    Yanai, Nobuhiro
    Mizuno, Motohiro
    Ando, Hideo
    Kitagawa, Susumu
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (11) : 5083 - 5089
  • [3] Theoretical study on high-spin to low-spin transition of {Fe(pyrazine)[Pt(CN)4]}: Guest-induced entropy decrease
    Ando, Hideo
    Nakao, Yoshihide
    Sato, Hirofumi
    Ohba, Masaaki
    Kitagawa, Susumu
    Sakaki, Shigeyoshi
    [J]. CHEMICAL PHYSICS LETTERS, 2011, 511 (4-6) : 399 - 404
  • [4] Guest Modulation of Spin-Crossover Transition Temperature in a Porous Iron(II) Metal-Organic Framework: Experimental and Periodic DFT Studies
    Aravena, Daniel
    Arcis Castillo, Zulema
    Carmen Munoz, M.
    Gaspar, Ana B.
    Yoneda, Ko
    Ohtani, Ryo
    Mishima, Akio
    Kitagawa, Susumu
    Ohba, Masaaki
    Antonio Real, Jose
    Ruiz, Eliseo
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2014, 20 (40) : 12864 - 12873
  • [5] The Effect of an Active Guest on the Spin Crossover Phenomenon
    Bao, Xin
    Shepherd, Helena J.
    Salmon, Lionel
    Molnar, Gabor
    Tong, Ming-Liang
    Bousseksou, Azzedine
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (04) : 1198 - 1202
  • [6] Spin-crossover nanocrystals with magnetic, optical, and structural bistability near room temperature
    Boldog, Ishtvan
    Gaspar, Ana B.
    Martinez, Victor
    Pardo-Ibanez, Pablo
    Ksenofontov, Vadim
    Bhattacharjee, Ashis
    Guetlich, Philipp
    Real, Jose A.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (34) : 6433 - 6437
  • [7] One shot laser pulse induced reversible spin transition in the spin-crossover complex [Fe(C4H4N2]{Pt(CN)4}] at room temperature
    Bonhommeau, S
    Molnár, G
    Galet, A
    Zwick, A
    Real, JA
    McGarvey, JJ
    Bousseksou, A
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (26) : 4069 - 4073
  • [8] Molecular spin crossover phenomenon: recent achievements and prospects
    Bousseksou, Azzedine
    Molnar, Gabor
    Salmon, Lionel
    Nicolazzi, William
    [J]. CHEMICAL SOCIETY REVIEWS, 2011, 40 (06) : 3313 - 3335
  • [9] Semiconductor nanocrystals as fluorescent biological labels
    Bruchez, M
    Moronne, M
    Gin, P
    Weiss, S
    Alivisatos, AP
    [J]. SCIENCE, 1998, 281 (5385) : 2013 - 2016
  • [10] Bureekaew S, 2009, NAT MATER, V8, P831, DOI [10.1038/NMAT2526, 10.1038/nmat2526]
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