Relationship between coking pressure generated by coal blends and the composition of their primary tars

被引:15
作者
Barriocanal, C. [1 ]
Diez, M. A. [1 ]
Alvarez, R. [1 ]
Casal, M. D. [1 ]
机构
[1] CSIC, Inst Nacl Carbon, INCAR, E-33080 Oviedo, Spain
关键词
Coal blends; Pyrolysis; Coking pressure; Primary tars; CARBONIZATION PHASES; PYROLYSIS;
D O I
10.1016/j.jaap.2008.09.007
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Four coals that develop different pressures during the coking process were selected together with 10 blends (7 binary and 3 ternary) prepared with the same coals. Their semicoke contraction/expansion was measured by means of two tests (the Koppers-INCAR and the sole heated oven) and the variation in coking pressure during coking was determined in a movable wall oven. The coals and blends were then pyrolysed and the tars were analysed by gas chromatography (GC-FID-MS). The additivity law was applied to the properties used to evaluate the dangerousness of the blends and to the composition of the tar produced from the blends. Afterwards, the composition of the tar was studied in relation to contraction/expansion and the coking pressure generated by the coals and blends. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:514 / 520
页数:7
相关论文
共 26 条
[1]  
ALVAREZ R, 1991, COKEMAKING INT, V1, P37
[2]   A laboratory study of the mechanism of coking pressure generation [J].
Barriocanal, C ;
Hays, D ;
Patrick, JW ;
Walker, A .
FUEL, 1998, 77 (07) :729-733
[3]   The laboratory identification of dangerously coking coals [J].
Barriocanal, C ;
Patrick, JW ;
Walker, A .
FUEL, 1998, 77 (08) :881-884
[4]   Influence of porosity and fissuring on coking pressure generation [J].
Casal, M. D. ;
Barriocanal, C. ;
Diez, M. A. ;
Alvarez, R. .
FUEL, 2008, 87 (12) :2437-2443
[5]   Influence of the permeability of the coal plastic layer on coking pressure [J].
Casal, MD ;
Díaz-Faes, E ;
Alvarez, R ;
Díez, MA ;
Barriocanal, C .
FUEL, 2006, 85 (03) :281-288
[6]   Low-temperature pyrolysis of coals with different coking pressure characteristics [J].
Casal, MD ;
Canga, CS ;
Díez, MA ;
Alvarez, R ;
Barriocanal, C .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2005, 74 (1-2) :96-103
[7]   Characterization of different origin coking coals and their blends by Gieseler plasticity and TGA [J].
Diaz-Faes, E. ;
Barriocanal, C. ;
Diez, M. A. ;
Alvarez, R. .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2007, 80 (01) :203-208
[8]  
ELLIOTT MA, CHEM COAL UTILIZAT S
[9]   INFLUENCE OF AIR OXIDATION ON THE PRESSURE EXERTED BY COKING COALS DURING CARBONIZATION [J].
ESCUDERO, JB ;
ALVAREZ, R .
FUEL, 1981, 60 (03) :251-253
[10]  
GRANSDEN JA, 1990, COKE OVEN WALL PRESS, P107