Synthesis, structure, and magnetic properties of a large lanthanide-transition-metal single-molecule magnet

被引：515
作者：
Zaleski, CM
Depperman, EC
Kampf, JW
Kirk, ML
Pecoraro, VL
机构：
[1] Univ New Mexico, Dept Chem, Albuquerque, NM 87131 USA
[2] Univ Michigan, Dept Chem, Willard H Dow Labs, Ann Arbor, MI 48109 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 30期
关键词：
cluster compounds; dysprosium; lanthanicles; magnetic properties; manganese;
D O I：
10.1002/anie.200454013
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The largest known Dy-Mn complex is [DyIII6Mn III4MnIV2(H2shi) 4(Hshi)2(Shi)10] (H3shi is salicylhydroxamic acid; see stereopicture). The Dy ions are arranged in a nearly planar hexagonal ring and are capped on opposite sides by a Mn III2MnIV trimer. This mixed-metal topology provides a new structure class for the examination of interesting magnetic phenomena of individual molecules.
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页码：3912 / 3914
页数：3
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