Na(Y1.5Na0.5)F6 single-crystal nanorods as multicolor luminescent materials

被引:339
作者
Wang, Leyu
Li, Yadong [1 ]
机构
[1] Tsing Hua Univ, Dept Chem, Beijing 100084, Peoples R China
[2] Anhui Normal Univ, Anhui Key Lab Funct Mol Solids, Coll Chem & Mat Sci, Wuhu 241000, Peoples R China
关键词
D O I
10.1021/nl060684u
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A facile wet chemical synthesis method was used to prepare a range of single-crystal Na(Y1.5Na0.5)F-6 nanorods with controllable aspect ratios. Their novel multicolor upconversion (UC) fluorescence has been successfully realized by doping Yb3+/Er3+ (green) and Yb3+/Tm3+ (blue) ion pairs. When doped with Eu3+ and Tb3+ ions, the strong red and green downconversion (DC) fluorescence has also been observed, respectively. Being covered with oleic acids, these luminescent nanorods have been transparently dispersed in nonpolar solvent. For their unique luminescence and controllable morphology and surface properties, these nanorods may find great applications in the fields of color displays, biolabels, light-emitting diodes (LEDs), optical storage, optoelectronics, anticounterfeiting, and solid-state lasers.
引用
收藏
页码:1645 / 1649
页数:5
相关论文
共 37 条
[1]   Photochemical instability of CdSe nanocrystals coated by hydrophilic thiols [J].
Aldana, J ;
Wang, YA ;
Peng, XG .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (36) :8844-8850
[2]   Near-infrared optical sensors based on single-walled carbon nanotubes [J].
Barone, PW ;
Baik, S ;
Heller, DA ;
Strano, MS .
NATURE MATERIALS, 2005, 4 (01) :86-U16
[3]   Electron transport in very clean, as-grown suspended carbon nanotubes [J].
Cao, J ;
Wang, Q ;
Dai, H .
NATURE MATERIALS, 2005, 4 (10) :745-749
[4]   Nanowire nanosensors for highly sensitive and selective detection of biological and chemical species [J].
Cui, Y ;
Wei, QQ ;
Park, HK ;
Lieber, CM .
SCIENCE, 2001, 293 (5533) :1289-1292
[5]   A three-color, solid-state, three-dimensional display [J].
Downing, E ;
Hesselink, L ;
Ralston, J ;
Macfarlane, R .
SCIENCE, 1996, 273 (5279) :1185-1189
[6]   Single-nanowire electrically driven lasers [J].
Duan, XF ;
Huang, Y ;
Agarwal, R ;
Lieber, CM .
NATURE, 2003, 421 (6920) :241-245
[7]   Single-crystal gallium nitride nanotubes [J].
Goldberger, J ;
He, RR ;
Zhang, YF ;
Lee, SW ;
Yan, HQ ;
Choi, HJ ;
Yang, PD .
NATURE, 2003, 422 (6932) :599-602
[8]   Growth of nanowire superlattice structures for nanoscale photonics and electronics [J].
Gudiksen, MS ;
Lauhon, LJ ;
Wang, J ;
Smith, DC ;
Lieber, CM .
NATURE, 2002, 415 (6872) :617-620
[9]   Air-stable all-inorganic nanocrystal solar cells processed from solution [J].
Gur, I ;
Fromer, NA ;
Geier, ML ;
Alivisatos, AP .
SCIENCE, 2005, 310 (5747) :462-465
[10]   Highly efficient multicolour upconversion emission in transparent colloids of lanthanide-doped NaYF4 nanocrystals [J].
Heer, S ;
Kömpe, K ;
Güdel, HU ;
Haase, M .
ADVANCED MATERIALS, 2004, 16 (23-24) :2102-+