On the chiroptical properties of racemic crystals

被引:14
作者
Kahr, Bart [1 ,2 ]
Martin, Alexander T. [1 ,2 ]
Ernst, Karl-Heinz [3 ]
机构
[1] NYU, Dept Chem, 100 Washington Sq East, New York, NY 10003 USA
[2] NYU, Inst Mol Design, 100 Washington Sq East, New York, NY 10003 USA
[3] Empa, Uberlandstr 129, Dubendorf, Switzerland
基金
美国国家卫生研究院; 美国国家科学基金会;
关键词
circular birefringence; circular dichroism; Mueller matrix; optical activity; optical rotation; racemates; CIRCULAR-DICHROISM SPECTRA; OPTICAL-ACTIVITY; SINGLE-CRYSTAL; BIREFRINGENCE; TRANSMISSION; POLARIZATION; POLARIMETRY; COMPLEXES; APPARATUS;
D O I
10.1002/chir.22820
中图分类号
R914 [药物化学];
学科分类号
100701 ;
摘要
In a recent letter on the Optical activity from racemates, discussed at the 16th International Conference on Chiroptical Spectroscopy in Rennes (June 2017), scientists claimed to have measured the circular dichroism of colored, racemic crystals of two transition metal complexes, observations that serve to correct a clear deficit in our understanding of the optical properties of racemates. In fact, there is no deficit in our understanding of the optical properties of racemates. Moreover, the measurements presented are unconvincing as evidence of circular dichroism measured in anisotropic crystals and therefore do not inform our understanding of the specific crystals investigated, or racemates generally speaking.
引用
收藏
页码:378 / 382
页数:5
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