Synthesis of cobalt bis(8-methylthio-1,2-dicarbollide)-pentacarbonyltungsten complexes

被引：7

作者：

Timofeev, S. V. ^{[1
]}

Anufriev, S. A. ^{[1
]}

Sivaev, I. B. ^{[1
]}

Bregadze, V. I. ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, 28 Ul Vavilova, Moscow 119991, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2018年 / 67卷 / 03期

基金：

俄罗斯科学基金会;

关键词：

cobalt bis(dicarbollide); methylthio derivatives; tungsten pentacarbonyl; complexes; CARBONYL SIGMA-COMPLEXES; MOLECULAR MOTORS; METAL-CARBONYLS; METALLACARBORANE; FLUORESCENCE; SPECTROSCOPY; MACHINES; MOTION; LIGAND;

D O I：

10.1007/s11172-018-2112-9

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A reaction of Bu4N[8,8'-(MeS)(2)-3,3'-Co(1,2-C2B9H10)(2)] with (MeCN)(3)W(CO)(3) in dichloromethane gave a mixture of Bu4N{(CO)(5)W[kappa-8,8'-(MeS)(2)-3,3'-Co(1,2-C2B9H10)(2)]} and Bu4N{[(CO)(5)W](2)[kappa(2)-8,8'-(MeS)(2)-3,3'-Co(1,2-C2B9H10)(2)]}, which were separated by column chromatography on silica gel.

引用

页码：570 / 572

页数：3

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