Synthesis of cobalt bis(8-methylthio-1,2-dicarbollide)-pentacarbonyltungsten complexes

被引：7
|
作者：
Timofeev, S. V. [1 ]
Anufriev, S. A. [1 ]
Sivaev, I. B. [1 ]
Bregadze, V. I. [1 ]
机构：
[1] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, 28 Ul Vavilova, Moscow 119991, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2018年 / 67卷 / 03期
基金：
俄罗斯科学基金会;
关键词：
cobalt bis(dicarbollide); methylthio derivatives; tungsten pentacarbonyl; complexes; CARBONYL SIGMA-COMPLEXES; MOLECULAR MOTORS; METAL-CARBONYLS; METALLACARBORANE; FLUORESCENCE; SPECTROSCOPY; MACHINES; MOTION; LIGAND;
D O I：
10.1007/s11172-018-2112-9
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A reaction of Bu4N[8,8'-(MeS)(2)-3,3'-Co(1,2-C2B9H10)(2)] with (MeCN)(3)W(CO)(3) in dichloromethane gave a mixture of Bu4N{(CO)(5)W[kappa-8,8'-(MeS)(2)-3,3'-Co(1,2-C2B9H10)(2)]} and Bu4N{[(CO)(5)W](2)[kappa(2)-8,8'-(MeS)(2)-3,3'-Co(1,2-C2B9H10)(2)]}, which were separated by column chromatography on silica gel.
引用
收藏
页码：570 / 572
页数：3
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