Thio- and selenosulfonato complexes of iron bearing aromatic and heterocyclic groups

被引：8

作者：

El-khateeb, Mohammad ^{[1
]}

Asali, Khalil J. ^{[1
]}

Al-Noaimi, Mousa ^{[2
]}

Al-Rabaee, Enas ^{[1
]}

Awwadi, Firas F. ^{[3
]}

Taher, Deeb ^{[3
]}

Korb, Marcus ^{[4
]}

Lang, Heinrich ^{[4
]}

机构：

[1] Jordan Univ Sci & Technol, Dept Chem, Irbid 22110, Jordan

[2] Hashemite Univ, Dept Chem, Zarqa 13115, Jordan

[3] Univ Jordan, Dept Chem, Amman 11942, Jordan

[4] Tech Univ Chemnitz, Inst Chem, D-09107 Chemnitz, Germany

来源：

INORGANICA CHIMICA ACTA | 2014年 / 421卷

关键词：

Iron; Carbonyls; X-ray structure; Chalcogenosulfonate; Characterization; ORGANOMETALLIC SULFUR COMPLEXES; S-BONDED MONOTHIOCARBOXYLATES; CRYSTAL-STRUCTURE; CARBOXYLATE COMPLEXES; SELENOCARBOXYLATE; DERIVATIVES; REACTIVITY; MONO;

D O I：

10.1016/j.ica.2014.07.021

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Various new thio-and selenosulfonato complexes of iron were synthesized by straight forward route. Treatment of the iron chalcogenides, (mu-E-x)[CpFe(CO)(2)](2) (E = S; x = 2-4, E = Se; x = 1) with sulfonyl chlorides produced the corresponding thio-or selenosulfonato complexes CpFe(CO)(2)ESO2Ar [Ar = 2-C4H3S (1), 5-C4H2SCl (2), 1,3-C6H4SO2Cl (3), 1,3-C6H4CO2H (4); E = S (a), Se (b)]. The dimers [CpFe(CO)(2) ESO2](2)(1,3-C6H4) (5) are obtained from the iron chalcogenides with 1,3-C6H4(SO2Cl) 2 in a 2:1 molar ratio. All of these new complexes have been characterized by IR, H-1, C-13 NMR spectroscopy, UV-Vis and elemental analysis. The X-ray structure of CpFe(CO)(2)ESO2-1,3-C6H4SO2Cl (3a) is determined. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：553 / 558

页数：6

共 32 条

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