A novel helical chain zinc(II) coordination polymer derived from both ferrocenecarboxylato and bibenzimidazolyl ligands: synthesis, crystal structure and properties

被引：28

作者：

Li, G ^{[1
]}

Li, ZF ^{[1
]}

Hou, HW ^{[1
]}

Meng, XR ^{[1
]}

Fan, YT ^{[1
]}

Chen, WH ^{[1
]}

机构：

[1] Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Peoples R China

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2004年 / 694卷 / 1-3期

基金：

中国国家自然科学基金;

关键词：

zinc(II); crystal structure; coordination polymer; ferrocenecarboxylate; thermal and electrochemical properties;

D O I：

10.1016/j.molstruc.2004.03.020

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A novel zinc(II) coordination polymer {[Zn(FcCOO)(2)(bbbm)](.)2H(2)O}(n) (Fc = (eta(5)-C5H5)Fe(eta(5)-C5H4); bbbm = 1,1'-(1,4-butanediyl)-bis-1H-benzimidazole) was obtained by the reaction of Zn(OAc)(2)(.)2H(2)O with bbbm and FcCOONa in methanol solution. The molecule reveals an infinite one-dimensional (ID) helical chain [Zn(bbbm)],, with the ferrocenecarboxylate anion as monodentate coordinating to the Zn ion. Its thermal and electrochemical properties were also investigated. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：179 / 183

页数：5

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