A novel helical chain zinc(II) coordination polymer derived from both ferrocenecarboxylato and bibenzimidazolyl ligands: synthesis, crystal structure and properties

被引：28
作者：
Li, G [1 ]
Li, ZF [1 ]
Hou, HW [1 ]
Meng, XR [1 ]
Fan, YT [1 ]
Chen, WH [1 ]
机构：
[1] Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Peoples R China
来源：
JOURNAL OF MOLECULAR STRUCTURE | 2004年 / 694卷 / 1-3期
基金：
中国国家自然科学基金;
关键词：
zinc(II); crystal structure; coordination polymer; ferrocenecarboxylate; thermal and electrochemical properties;
D O I：
10.1016/j.molstruc.2004.03.020
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A novel zinc(II) coordination polymer {[Zn(FcCOO)(2)(bbbm)](.)2H(2)O}(n) (Fc = (eta(5)-C5H5)Fe(eta(5)-C5H4); bbbm = 1,1'-(1,4-butanediyl)-bis-1H-benzimidazole) was obtained by the reaction of Zn(OAc)(2)(.)2H(2)O with bbbm and FcCOONa in methanol solution. The molecule reveals an infinite one-dimensional (ID) helical chain [Zn(bbbm)],, with the ferrocenecarboxylate anion as monodentate coordinating to the Zn ion. Its thermal and electrochemical properties were also investigated. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码：179 / 183
页数：5
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